Sarmientite

Fe3+2(AsO4)(SO4)(OH) · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Smi
Discovered
1941
Also known as
  • Sarmientiet

Where it forms, where it's found

Geological setting

Fe-sulfate gossan over pyrite vein.

Type locality
Santa Elena Mine
  1. Quebrada Alcaparrosa
  2. Calingasta
  3. Calingasta Department
  4. San Juan Province
  5. Argentina

-31.3419°, -69.4092°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Translucent
Colour
Light yellow-orange
Density
2.58 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38° · 2V calc = 38°
Refractive index
1.628 – 1.698
Surface relief
High
Principal indices
nα 1.628 · nβ 1.635 · nγ 1.698
Dispersion
weak to distinct
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 6.55 Å · b = 18.55 Å · c = 9.70 Å
Cell angles
β = 97.65 °
Ratio a:b:c
1 : 2.832 : 1.481
Z
4
Morphology

Crystals prismatic [001] and flattened (010), exhibiting (010), (110) and (011). Microcrystalline (to 20 μm) forming nodular masses as aggregates.

Type-locality form

Pure, irregular nodules made up of minute prismatic crystals to 25 microns in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
49.36%
26FeIronIron255.845111.690
24.62%
33AsArsenicArsenic174.92274.922
16.51%
16SSulfurSulfur132.06032.060
7.07%
1HHydrogenHydrogen111.00811.088
2.44%
Total453.746100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Sarmientiet

In other languages

German
Sarmientit
Italian
Sarmientite

Classification

Strunz
10th ed.

8.DB.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.35SarmientiteSpecies
Dana
8th ed.

43.05.01.01

  • 43Compound Phosphates, Etc.Class
  • 43.05Hydrated Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.05.01Sarmientite GroupGroup
  • 43.05.01.01SarmientiteSpecies
CIM

22.3.26

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.26SarmientiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1941Angelelli, V., Gordon, S.G. (1941) Sarmientite, a new mineral from Argentina. Notulae Naturae of The Academy of Natural Sciences of Philadelphia: 92: 1-4.
  2. 1942Fleischer, M. (1942) New mineral names. American Mineralogist, 27 (4). 333-334
  3. 1942Angelelli and Gordon (1942) Publ. Inst. de Fisiog. y Geol., Univ. Nac. del Litoral, Argentina: no. XII.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1968de Abeledo, M. E. J., de Benyacar, M. A. R. (1968) New data on sarmientite. American Mineralogist, 53 (11-12) 2077-2081
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sarmientite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sarmientite-3536},
  note      = {Accessed 2026-05-11}
}