Zýkaite

Fe3+4(AsO4)3(SO4)(OH) · 15H2O
IMA status
  • Approved
IMA symbol
Zýk
Discovered
1976
IMA approved
1976
Also known as
  • IMA1976-039

Where it forms, where it's found

Geological setting

alteration product of arsenopyrite and pyrite

Type locality
Šafary Mine
  1. Kaňk
  2. Kutná Hora
  3. Kutná Hora District
  4. Central Bohemian Region
  5. Czech Republic

49.9786°, 15.2675°

11recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Greyish white · light yellow · light green
Streak
Pale yellowish
Tenacity
waxy
Fracture
Irregular/Uneven
Density
2.50 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60° · 2V calc = 56 – 66°
Refractive index
1.632 – 1.646
Surface relief
Moderate
Principal indices
nα 1.632 · nβ 1.635 – 1.636 · nγ 1.646
Dispersion
weak to distinct
Michel-Lévy diagramhighlighted lineδ = 0.0140
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]140 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation140 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#45
Cell parameters
a = 20.853(20) Å · b = 7.033(4) Å · c = 36.991(23) Å
Ratio a:b:c
1 : 0.337 : 1.774
Z
8

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3215.999511.968
50.03%
33AsArsenicArsenic374.922224.766
21.96%
26FeIronIron455.845223.380
21.83%
16SSulfurSulfur132.06032.060
3.13%
1HHydrogenHydrogen311.00831.248
3.05%
Total1023.422100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1976-039

In other languages

French
Zykaite
German
IMA 1976-039 · Zýkait
Spanish
Zykaíta
Italian
zýkaite
Chinese
水硫砷铁石

Classification

Strunz
10th ed.

8.DB.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DBWith only medium-sized cations, (OH, etc.):RO4< 1:1Group
  • 8.DB.45ZýkaiteSpecies
Dana
8th ed.

43.05.03.02

  • 43Compound Phosphates, Etc.Class
  • 43.05Hydrated Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.05.03Pitticite GroupGroup
  • 43.05.03.02ZýkaiteSpecies
CIM

22.3.28

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.28ZýkaiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1978Fleischer, Michael (1978) New mineral names. American Mineralogist, 63 (11-12). 1282-1284
  2. 1978Čech, F., Praha, J., Novak, F. (1978) Zýkaite, Fe3+4(AsO4)3(SO4)(OH)·15H2O, a new mineral. Neues Jahrbuch für Mineralogie - Monatshefte, 1978. 134-144
  3. 2005(2005) Zýkaite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2011Frost, Ray L., Palmer, Sara J., Xi, Yunfei (2011) Vibrational spectroscopy of the multi-anion mineral zykaite Fe4(AsO4)(SO4)(OH)·15H2O - implications for arsenate removal. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 83 (1) 444-448 doi:10.1016/j.saa.2011.08.062DOI: 10.1016/j.saa.2011.08.062
  5. 2015Majzlan, Juraj, Amoako, Felix Y., Kindlová, Helena, Drahota, Petr (2015) Thermodynamic properties of zýkaite, a ferric sulfoarsenate. Applied Geochemistry, 61. 294-301 doi:10.1016/j.apgeochem.2015.06.007DOI: 10.1016/j.apgeochem.2015.06.007
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zýkaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zykaite-4437},
  note      = {Accessed 2026-05-11}
}