Shiranuiite

Cu+(Rh3+Rh4+)S4
IMA status
  • Approved
IMA symbol
Sir
Also known as
  • Shiranuiiet

Where it forms, where it's found

Geological setting

The clinopyroxenite mass has a depression near the center, and a small river, approximately 2-3 m wide and 2 km long, passes through this area and joins the Shakain River. PGM can be collected as a placer in this small river. Most of the PGM placer collected was composed of isoferroplatinum-based grains that are irregularly shaped with an average size of less than 1 mm, although grains up to 4 mm were also obtained.

Type locality
Haraigawa
  1. Misato
  2. Shimomashiki District
  3. Kumamoto Prefecture
  4. Japan

32.5726°, 130.7905°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Tenacity
brittle
Cleavage
Poor/Indistinct

estimated to be along the (111) planes according to the isotypic malanite

Density
5.78 g/cm³

Optical

Optical colour
a bluish gray color
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation

Crystallography

Crystal system
Isometric
Space group
Fd-3m
Cell parameters
a = 9.757(2) Å
Z
8
Type-locality form

Isoferroplatinum-based grains are often accompanied by black to gray colored nubs from 20 to 500 μm in size. Shiranuiite and cuprorhodsite occur as dominant minerals of such nubs, although both are indistinguishable based on the occurrence mode and can only be distinguished by chemical analysis.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
45RhRhodiumRhodium2102.906205.812
51.77%
16SSulfurSulfur432.060128.240
32.25%
29CuCopperCopper163.54663.546
15.98%
Total397.598100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Shiranuiiet

In other languages

German
Shiranuiit
Italian
Shiranuiite
Japanese
不知火鉱

Classification

Strunz
10th ed.

2.DA.05

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DAM:S = 3:4Group
  • 2.DA.05ShiranuiiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Nishio-Hamane, D., Tanaka, T., and Shinmachi, T.: Shiranuiite, IMA 2023-072a, in: CNMNC Newsletter 78, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-361-2024, 2024.
  2. 2024NISHIO-HAMANE, Daisuke, SAITO, Katsuyuki (2024) Ezochiite, Cu+(Rh3+Pt4+)S4, a new mineral in the thiospinel group from Hokkaido, Japan. Journal of Mineralogical and Petrological Sciences, 119 (1). 240304 doi:10.2465/jmps.240304DOI: 10.2465/jmps.240304
  3. 2025Cabri, Louis J.; McDonald, Andrew M. (2025) Ezochiite and shiranuiite are cuprorhodsite and are not new mineral species. American Mineralogist, 110 (6). 941-944 doi:10.2138/am-2024-9517DOI: 10.2138/am-2024-9517
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Shiranuiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/shiranuiite-471057},
  note      = {Accessed 2026-05-11}
}