Toyohaite

Ag1+(Fe2+0.5Sn4+1.5)S4
IMA status
  • Approved
IMA symbol
To
Discovered
1989
IMA approved
1989
Also known as
  • Ag-rhodostannit
  • Ag-Rhodostannite
  • IMA1989-007
  • +1 more

Where it forms, where it's found

Geological setting

Silver-lead-zinc deposit in hydrothermally altered volcanic, pyroclastic and sedimentary rocks.

Type locality
Toyoha Mine
  1. Minami-ku
  2. Sapporo City
  3. Ishikari Subprefecture
  4. Hokkaidō Prefecture
  5. Japan

42.9800°, 141.0411°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Gray-brown
Density
7.25 g/cm³

Optical

Optical colour
Brownish grey
Anisotropism
Distinct to strong, greenish gray to reddish brown
Bireflectance
Very weak
Internal reflections
None
Tropism
Anisotropic
Reflectance R%
(23.5, 24.3) 480, (24.1, 26.1) 546, (24.7, 26.4) 589, (26.5, 28.3) 650
Reflected-light panel
24.7 %anisotropic · dual curve
Specimen sRGB 185, 124, 66
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Very weak
Anisotropism
Distinct to strong, greenish gray to reddish brown
Reflected colour
Brownish grey
Internal reflections
None

Crystallography

Crystal system
Tetragonal
Space group
#136
Cell parameters
a = 7.464(3) Å · c = 10.80(2) Å
Morphology

Tiny grains.

Twinning

Twinning is recognized under high magnification.

Type-locality form

Aggregates of small crystals whose individual grain size ranges from 1 to 30 µm.

Comment

Original description; space group assumed by comparison to rhodostannite.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
50SnTinTin1.5118.710178.065
40.28%
16SSulfurSulfur432.060128.240
29.01%
47AgSilverSilver1107.868107.868
24.40%
26FeIronIron0.555.84527.922
6.31%
Total442.096100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • Zn
  • Cd

Synonyms

  • Ag-rhodostannit
  • Ag-Rhodostannite
  • IMA1989-007
  • Toyohaiet

In other languages

German
IMA 1989-007 · Toyohait
Italian
Toyohaite
Japanese
豊羽鉱

Classification

Strunz
10th ed.

2.DA.10

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DAM:S = 3:4Group
  • 2.DA.10ToyohaiteSpecies
Dana
8th ed.

02.10.03.02

  • 02SulfidesClass
  • 02.10AmBnXp, with (m+n):p = 3:4Type
  • 02.10.03— unnamed intermediate level —Group
  • 02.10.03.02ToyohaiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1991YAJIMA, Junkichi, OHTA, Eijun, KANAZAWA, Yasuo (1991) Toyohaite, Ag2FeSn3S8, a new mineral. Mineralogical Journal, 15 (5) 222-232 doi:10.2465/minerj.15.222 DOI: 10.2465/minerj.15.222
  2. 1992Jambor, John L., Puziewicz, Jacek (1992) New Mineral Names. American Mineralogist, 77 (9-10) 1116-1121
  3. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  4. 2005(2005) Toyohaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2019Bosi, Ferdinando, Biagioni, Cristian, Pasero, Marco (2019) Nomenclature and classification of the spinel supergroup. European Journal of Mineralogy, 31 (1) 183-192 doi:10.1127/ejm/2019/0031-2788 DOI: 10.1127/ejm/2019/0031-2788
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Toyohaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/toyohaite-4004},
  note      = {Accessed 2026-05-11}
}