Trippkeite

Cu2+As3+2O4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tpk
Discovered
1880
Also known as
  • Trippkeiet

Where it forms, where it's found

Geological setting

Copper deposit

Type locality
Copiapó Province
  1. Atacama
  2. Chile
7recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Brilliant greenish-blue · pistachio-green · pale bluish green in transmitted light · with neon-blue internal reflections.
Streak
Pale blue
Tenacity
flexible
Cleavage
Perfect

On (100), perfect; on (110), good.

Fracture
Micaceous
Density
4.8 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.9 – 2.12
Surface relief
Very high
Principal indices
nω 1.90 · nε 2.12
Birefringence
0.22
Pleochroism
Not Visible
Michel-Lévy diagramhighlighted lineδ = 0.2200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2200 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2200 nm
Order4th order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#187
Cell parameters
a = 8.592 Å · c = 5.573 Å
Z
4
Morphology

Crystals short prismatic to equant, exhibiting (021), (100), and (001) as dominant forms, plus four additional forms. Crystals may be bent.

Comment

Space group attribution based on synthetic material.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
54.02%
8OOxygenOxygen415.99963.996
23.07%
29CuCopperCopper163.54663.546
22.91%
Total277.386100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Trippkeiet

In other languages

German
Trippkeit
Italian
Trippkeite
Chinese
软砷铜矿

Classification

Strunz
10th ed.

4.JA.20

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JAArsenites, antimonites, bismuthites; without additional anions, without H2OGroup
  • 4.JA.20TrippkeiteSpecies
Dana
8th ed.

45.01.05.01

  • 45Acid and Normal Antimonites and ArsenitesClass
  • 45.01MiscellaneousType
  • 45.01.05— unnamed intermediate level —Group
  • 45.01.05.01TrippkeiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1880Damour, A., vom Rath, G. (1880) Ueber den Trippkeït, eine neue Mineralspecies. Zeitschrift für Krystallographie, 5 (23). 245 doi:10.1524/zkri.1880.5.23.245DOI: 10.1524/zkri.1880.5.23.245
  2. 1880vom Rath (1880) Berichte Niederrheinische Gesellschaft für Natur und Heilkunde, Bonn: 209.
  3. 1880Damour (1880) Bulletin de la Société française de Minéralogie: 3: 175-180.
  4. 1891Goldschmidt, Victor (1891) Index der Krystallformen der Mineralien Vol. 3. Springer Berlin Heidelberg. doi:10.1007/978-3-662-25554-4 DOI: 10.1007/978-3-662-25554-4
  5. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Trippkeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/trippkeite-4023},
  note      = {Accessed 2026-05-11}
}