Minium

Pb2+2Pb4+O4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mnm
Discovered
1806
Also known as

Where it forms, where it's found

Geological setting

A rare secondary alteration mineral. Also formed during mine fires.

245recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Greasy
Transparency
Translucent
Colour
Red · brownish-red · yellowish tint at times · red in transmitted light.
Streak
Orange-yellow
Density
8.9 g/cm³

Optical

Optical type
Uniaxial
Refractive index
2.41 – 2.42
Surface relief
Very high
Principal indices
nω 2.42 · nε 2.41
Pleochroism
Strong

X = deep reddish brown, Z = nearly colourless

Extinction
Extinction parallel, elongation negative
Notes

may be weakly birefringent with anomalous green interference colors.

Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
P42/mbc
Cell parameters
a = 8.811(5) Å · c = 6.563(3) Å
Z
4
Morphology

Massive, earthy, powdery. Microscopic crystalline scales.

Type-locality form

Disseminated, powdery to flaky

Comment

On synthetic material.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
90.67%
8OOxygenOxygen415.99963.996
9.33%
Total685.596100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Menie
  • Mennig
  • Mennige
  • Red Lead

In other languages

French
minium
German
Bleimennige · Menig · Mennige · Minig · Minium · rotes Bleioxid
Spanish
minio · minio de Levante · rojo de plomo · rojo Saturno
Italian
Minio
Japanese
ミニウム
Chinese
铅丹
Russian
Сурик · Сурик (минерал)
Arabic
إسرنج · اسرنج · الإسرنج · الاسرنج · الرصاص الأحمر · الرصاص الاحمر · السلقون · رصاص أحمر · رصاص احمر · سلقون

Classification

Strunz
10th ed.

4.BD.05

  • 4OxidesClass
  • 4.BMetal: Oxygen = 3:4 and similarDivision
  • 4.BDWith only large cationsGroup
  • 4.BD.05MiniumSpecies
Dana
8th ed.

07.02.08.01

  • 07Multiple OxidesClass
  • 07.02AB2X4Type
  • 07.02.08— unnamed intermediate level —Group
  • 07.02.08.01MiniumSpecies
CIM

7.11.22

  • 7Oxides and HydroxidesClass
  • 7.11Oxides of Sn and PbGroup
  • 7.11.22MiniumSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1806Smithson, J. (1806) Account of a discovery of native minium. Philosophical Transactions of the Royal Society of London: 96: 267-268.
  2. 1875Blunt, Thomas P. (1875) Notice on the analysis of minium or red lead. The Chemical News: 32: 3-4.
  3. 1932Darbyshire, J.A. (1932) An X-ray examination of the oxides of lead. Journal of the Chemical Society of London: 211-219.
  4. 1943Gross, S. T. (1943) The Crystal Structure of Pb3O4. Journal Of The American Chemical Society, 65 (6) 1107-1110 doi:10.1021/ja01246a029DOI: 10.1021/ja01246a029
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Minium — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/minium-2721},
  note      = {Accessed 2026-05-11}
}