Tvrdýite

Fe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2O
IMA status
  • Approved
IMA symbol
Tvr
IMA approved
2014
Also known as
  • IMA2014-082
  • Tvrdýiet

Where it forms, where it's found

Geological setting

Cavity in quartz gangue.

Type locality
Huber stock (Huber shaft
  1. Hub stock)
  2. Krásno
  3. Sokolov District
  4. Karlovy Vary Region
  5. Czech Republic

50.1227°, 12.8000°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Silvery to olive-greyish-green
Streak
Greyish-white
Tenacity
very brittle
Cleavage
Distinct/Good

(100)

Fibres are somewhat flexible.

Density
2.834 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 56°
Refractive index
1.65 – 1.677
Surface relief
High
Principal indices
nα 1.650 · nβ 1.671 · nγ 1.677
Pleochroism
Strong

X = greenish-blue; Y = Z = yellowish-orange.

Dispersion
strong (r > v)
Notes

Absorption: X >> Y > Z .

Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 20.564(4) Å · b = 5.101(1) Å · c = 18.883(4) Å
Cell angles
β = 93.68(3) °
Ratio a:b:c
1 : 0.248 : 0.918
Unit cell volume
1976.7 ų
Z
4
Morphology

Acicular to fibrous crystals 0.5 - 5 μm in diameter and up to 300 μm long; may be in radiating aggregates, up to 3 mm.

Type-locality form

Acicular to fibrous; radiating aggregates.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2715.999431.973
52.59%
26FeIronIron355.845167.535
20.39%
15PPhosphorusPhosphorus430.974123.896
15.08%
13AlAluminiumAluminium326.98280.946
9.85%
1HHydrogenHydrogen171.00817.136
2.09%
Total821.486100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn
  • As
  • F

Synonyms

  • IMA2014-082
  • Tvrdýiet

In other languages

German
IMA 2014-082 · Tvrdýit
Italian
IMA2014-082 · tvrdýite

Classification

Strunz
10th ed.

8.DC.27

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.27TvrdýiteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2015Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05DOI: 10.1180/minmag.2015.079.1.05
  2. 2016Sejkora, J., Grey, I. E., Kampf, A. R., Price, J. R., Čejka, J. (2016) Tvrdýite, Fe2+Fe32+Al3(PO4)4(OH)5(OH2)4·2H2O, a new phosphate mineral from Krásno near Horní Slavkov, Czech Republic. Mineralogical Magazine, 80 (6) 1077-1088 doi:10.1180/minmag.2016.080.045 DOI: 10.1180/minmag.2016.080.045
  3. 2017(2017) Tvrdýite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2017Cámara, Fernando; Belakovskiy, Dmitriy I.; Uvarova, Yulia (2017) New Mineral Names. American Mineralogist, 102 (4). 916-920 doi:10.2138/am-2017-nmn10247DOI: 10.2138/am-2017-nmn10247
  5. 2020Vrtiška, Luboš; Malíková, Radana (2020) Nová data k výzkumu tvrdýitu z Krušné hory u Berouna (Česká republika). Bulletin Mineralogie Petrologie, 28 (2). 406-411 doi:10.46861/bmp.28.406DOI: 10.46861/bmp.28.406
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tvrdýite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tvrdyite-46532},
  note      = {Accessed 2026-05-11}
}