Volborthite

Cu3V2O7(OH)2 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vbo
Discovered
1837
Also known as
  • Knauffit
  • Knauffita
  • Knauffite
  • +8 more

Where it forms, where it's found

Geological setting

Oxidized zones of vanadium-bearing hydrothermal deposits.

Type locality
Sofronovskii Cu Mine
  1. Kalinino (Yugovskii Zavod)
  2. Kungursky District
  3. Perm Krai
  4. Russia
150recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Olive-green · yellow-green · green to yellow-green in transmitted light.
Cleavage
Perfect

One perfect.

Density
3.5 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 63 – 83°
Refractive index
1.793 – 1.816
Surface relief
Very high
Principal indices
nα 1.793 · nβ 1.801 · nγ 1.816
Pleochroism
Weak
Dispersion
r > v or r < v
Michel-Lévy diagramhighlighted lineδ = 0.0230
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]230 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation230 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.610(2) Å · b = 5.866(1) Å · c = 7.208(1) Å
Cell angles
β = 95.04(2) °
Ratio a:b:c
1 : 0.553 : 0.679
Z
2
Morphology

Pseudohexagonal. Scaly, fibrous or spongy crusts and rosette-like aggregates; also reticulated. Scales may have a triangular or hexagonal outline.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
40.17%
8OOxygenOxygen1115.999175.989
37.09%
23VVanadiumVanadium250.942101.884
21.47%
1HHydrogenHydrogen61.0086.048
1.27%
Total474.559100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Knauffit
  • Knauffita
  • Knauffite
  • Siberian volborthite
  • Usbekit
  • Uzbekite
  • Vanadate of Copper
  • Vanadinsaures Kupfer
  • Volborthiet
  • α-Uzbekite
  • β-Uzbekite

In other languages

French
Volborthite
German
Volborthit
Spanish
Volborthita
Italian
Volborthite
Chinese
水钒铜矿

Classification

Strunz
10th ed.

8.FD.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FDPolyphosphates, etc., with OH and H2OGroup
  • 8.FD.05VolborthiteSpecies
Dana
8th ed.

40.03.10.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.10— unnamed intermediate level —Group
  • 40.03.10.01VolborthiteSpecies
CIM

21.1.12

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.12VolborthiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1838Hess, H., Volborth, A. (1838) Ueber (das Volborthit), ein neues Vanadhaltiges Mineral. Bulletin Scientifique publié par L'Académie Impériale des Sciences de Saint-Pétersbourg: 4: 21-23.
  2. 1838Hess (1838) Journal für praktische Chemie, Leipzig: 14: 52.
  3. 1849Planer (1849) Archiv für wissenschaftliche Kunde: 8: 135 (as Knauffite).
  4. 1877Genth, F.A. (1877) On some tellurium and vanadium minerals. Proceedings of the American Philosophical Society: 17: 113-123.
  5. 1913Hillebrand, W.F., Merwin, H.E. (1913) Two varieties of calciovolborthite (?) from eastern Utah. American Journal of Science: 35(208): 441-445. (on material called Calciovolborthite = Tangeite)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Volborthite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/volborthite-4200},
  note      = {Accessed 2026-05-11}
}