Zaïrite

BiFe3+3(PO4)2(OH)6
IMA status
  • Approved
IMA symbol
Zaï
Discovered
1975
IMA approved
1975
Also known as
  • IMA1975-018
  • Zaireit
  • Zaireita
  • +2 more

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Eta-Etu
  1. Bapere
  2. Lubero Territory
  3. North Kivu
  4. DR Congo

0.3333°, 28.3333°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Green · light olive green
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.42 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.81 – 1.83
Surface relief
Very high
Principal indices
nω 1.82 – 1.83 · nε 1.81
Birefringence
Weak to moderate
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 7.015 Å · c = 16.365 Å
Z
3
Morphology

Found as irregular intersecting plates (<1 mm), perhaps fracture fillings with original mineral dissolved away.

Type-locality form

Medium to light olive green irregular plates.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
33.51%
83BiBismuthBismuth1208.980208.980
31.26%
26FeIronIron355.845167.535
25.06%
15PPhosphorusPhosphorus230.97461.948
9.27%
1HHydrogenHydrogen61.0086.048
0.90%
Total668.497100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca
  • Cu
  • Ba
  • S
  • Si
  • Te

Synonyms

  • IMA1975-018
  • Zaireit
  • Zaireita
  • Zaireite
  • Zaïriet

In other languages

French
Zaïrite
German
IMA 1975-018 · Zaïrit
Spanish
zaireíta · Zairita
Italian
Zaïrite

Classification

Strunz
10th ed.

8.BL.13

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BLWith medium-sized and large cations, (OH, etc.):RO4 = 3:1Group
  • 8.BL.13ZaïriteSpecies
Dana
8th ed.

41.05.12.03

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.12Waylandite GroupGroup
  • 41.05.12.03ZaïriteSpecies
CIM

19.14.33

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.33ZaïriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1975Van Wambeke, L. (1975) La zaïrite, un nouveau minéral appartenant à la série de la crandallite. Bulletin de Minéralogie, 98 (6) 351-353 doi:10.3406/bulmi.1975.7016DOI: 10.3406/bulmi.1975.7016
  2. 1977Fleischer, M., Mandarino, A. (1977) New mineral names. American Mineralogist, 62 (1-2). 173-176
  3. 1999Jambor, John L. (1999) Nomenclature of the alunite supergroup. The Canadian Mineralogist, 37 (6). 1323-1341
  4. 2005(2005) Zaïrite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2010Bayliss, P., Kolitsch, U., Nickel, E. H., Pring, A. (2010) Alunite supergroup: recommended nomenclature. Mineralogical Magazine, 74 (5) 919-927 doi:10.1180/minmag.2010.074.5.919 DOI: 10.1180/minmag.2010.074.5.919
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zaïrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zairite-4382},
  note      = {Accessed 2026-05-11}
}