Argentopyrite

AgFe2S3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Agpy
Discovered
1868
Also known as
  • Argentopyrita
  • Argentopyritt

Where it forms, where it's found

Geological setting

Hydrothermal veins

Type locality
Jáchymov
  1. Karlovy Vary District
  2. Karlovy Vary Region
  3. Czech Republic

50.3661°, 12.9233°

70recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Bronze-brown · tarnishing to lead-grey to blue-gray.
Streak
Grey.
Tenacity
brittle
Cleavage

None

Fracture
Irregular/Uneven
Density
4.25 g/cm³

Optical

Optical colour
Greyish to yellowish white
Anisotropism
Strong - deep blue to pale blue-grey
Tropism
Anisotropic
Reflectance R%
(20.5, 29.4) 400, (21.6, 30.2) 420, (22.7, 30.8) 440, (23.8, 31.6) 460, (24.6, 32.2) 480, (25.3, 32.8) 500, (25.8, 33.5) 520, (26.3, 34.1) 540, (26.8, 34.8) 560, (27.4, 35.6) 580, (28.1, 36.3) 600, (28.7, 36.9) 620, (29.4, 37.5) 640, (30.0, 38.0) 660, (30.4, 38.4) 680, (30.9, 38.7) 700
Luminescence
None
UV response
Not fluorescent in UV
Reflected-light panel
26.4 %anisotropic · dual curve
Specimen sRGB 195, 130, 64
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong - deep blue to pale blue-grey
Reflected colour
Greyish to yellowish white

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 6.6902(2) Å · b = 11.4497(4) Å · c = 6.4525(2) Å
Cell angles
β = 90.2420(8) °
Ratio a:b:c
1 : 1.711 : 0.964
Unit cell volume
494.26 ų
Z
4
Twinning

Pseudohexagonal twins, lamellar twins

Comment

Space group P1121/n (non-standard setting). Pseudo-orthorhombic. Originally assumed to have space group Pmmn, 6.639, 11.463, 6.452 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
35.38%
47AgSilverSilver1107.868107.868
34.16%
16SSulfurSulfur332.06096.180
30.46%
Total315.738100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • As

Synonyms

  • Argentopyrita
  • Argentopyritt

In other languages

French
Argentopyrite
German
Argentopyrit · Silberkies
Spanish
Argentopirita
Italian
Argentopirite

Classification

Strunz
10th ed.

2.CB.65

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.65ArgentopyriteSpecies
Dana
8th ed.

02.09.13.02

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.13Cubanite GroupGroup
  • 02.09.13.02ArgentopyriteSpecies
CIM

3.2.17

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.2Sulphides etc. of AgGroup
  • 3.2.17ArgentopyriteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1866von Waltershausen, W.S. (1866) Einige nachträgliche Bemerkungen über den Silberkies. Nachrichten von der Königlichen Gesellschaft der Wissenschaften und der Georg-Augusts-Universität: 9: 66-68.
  2. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  3. 1871Schrauf, A. (1871) Mineralogische Beobachtungen III. Sitzungsberichte der Mathematisch-Naturwissenschaftlichen Classe der Kaiserlichen Akademie der Wissenschaften: 114: 123-205.
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1954Murdoch, J., Berry, L. G. (1954) X-ray measurements on argentopyrite. American Mineralogist, 39 (5-6) 475-485
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Argentopyrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/argentopyrite-299},
  note      = {Accessed 2026-05-11}
}