Stephanite

Ag5SbS4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sph
Discovered
1845
Also known as
  • Antimonsilberglanz
  • Argent fragile
  • Argent noir
  • +22 more

Where it forms, where it's found

Geological setting

Late stage mineral in hydrothermal silver deposits.

Type locality
Freiberg
  1. Mittelsachsen
  2. Saxony
  3. Germany

50.9119°, 13.3428°

656recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Lead gray or black

Occasionally has a dull blue iridescence.

Streak
Iron black
Tenacity
brittle
Cleavage
Imperfect/Fair

[010] Imperfect, [021] Poor

Fracture
Sub-Conchoidal
Density
6.26 g/cm³

Optical

Pleochroism
Weak

White to pink-white

Optical colour
White-grey
Anisotropism
Strong, in vivid colors
Tropism
Anisotropic
Reflectance R%
(32.0–33.0) 400, (32.1–33.2) 420, (32.2–33.4) 440, (31.5–33.2) 460, (30.7–32.6) 480, (30.0–32.0) 500, (29.0–31.3) 520, (28.4–30.6) 540, (28.0–30.2) 560, (27.6–29.8) 580, (27.5–29.6) 600, (27.6–29.6) 620, (27.8–29.5) 640, (28.0–29.2) 660, (28.5–28.7) 680, (28.2–28.2) 700
Luminescence
None

Crystallography

Crystal system
Orthorhombic
Space group
#21
Cell parameters
a = 7.837(3) Å · b = 12.467(6) Å · c = 8.538(2) Å
Ratio a:b:c
1 : 1.591 : 1.089
Z
4
Morphology

Crystals short prismatic to tabular

Twinning

On (110); less common on (130)(100)(010).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver5107.868539.340
68.33%
16SSulfurSulfur432.060128.240
16.25%
51SbAntimonyAntimony1121.760121.760
15.42%
Total789.340100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As
  • Cu
  • Fe

Synonyms

  • Antimonsilberglanz
  • Argent fragile
  • Argent noir
  • Argent sulfuré fragile
  • Argento mineralisatum nigrum
  • Argentum mineralisatum nigrum
  • Black Silver
  • Brittle Silver Ore
  • Goldschmidtine
  • Melane-glance
  • Melanglance
  • Melanglanz
  • Plata agria
  • Prismatischer Melanglanz
  • Psaturose
  • Röschwächs
  • Rosicler negro
  • Schwarzgülden (of Wallerius)
  • Schwarzgültigerz
  • Schwarzsilberglanz
  • Sprödes Silberglanzerz (of Emmerling)
  • Sprödglanzerz
  • Stephaniet
  • Svartgylden
  • Tigererz

In other languages

French
Argent fragile · Argent noir · Psaturose · Stéphanite
German
Melanglanz · Stephanit
Spanish
Estefanita · Plata agria · Rosicler negro · Stephanita
Italian
Stefanite · Stephanite
Portuguese
Estefanita
Japanese
脆銀鉱
Russian
Стефанит

Classification

Strunz
10th ed.

2.GB.10

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GBNeso-sulfarsenites, etc. with additional SGroup
  • 2.GB.10StephaniteSpecies
Dana
8th ed.

03.02.04.01

  • 03SulfosaltsClass
  • 03.02ø = 4Type
  • 03.02.04Stephanite SeriesGroup
  • 03.02.04.01StephaniteSpecies
CIM

5.2.11

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.11StephaniteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1845Haidinger, W. (1845) Zweite Klasse: Geogenide. XIV. Ordnung. Glanze. VIII. Melanglanz. Stephanit. In: Handbuch der Bestimmenden Mineralogie. Braumüller und Seidel, Wien, 563-570 (570). http://rruff.info/uploads/HMB1845_563.pdf
  2. 1884Morton, Carl (1884) XI. Stephanit yon Kongsberg (Norwegen). Zeitschrift für Kristallographie - Crystalline Materials, 9 (1). 238-242 doi:10.1524/zkri.1884.9.1.238DOI: 10.1524/zkri.1884.9.1.238
  3. 1886Vrba, K. (1886). Beitrag zu einer Monographie des Stephanit. Kön. böhm. Gesellschaft der Wissenschaften, 79 pgs.
  4. 1889Miers, H. (1889) The Hemimorphism of Stephanite; The Crystalline Form of Kaolinite. Mineralogical Magazine, 91, 1-4.
  5. 1897Spencer, L. J. (1897) The Crystallography of Plagionite: New Crystal Forms on Stephanite, Enargite and Anglesite. Mineralogical Magazine and Journal of the Mineralogical Society, 11 (52) 192-197 doi:10.1180/minmag.1897.011.52.07 DOI: 10.1180/minmag.1897.011.52.07
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Stephanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/stephanite-3764},
  note      = {Accessed 2026-05-11}
}