Pyrargyrite

Ag3SbS3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pyg
Discovered
1831
Also known as
  • Aerosit
  • Aerosite
  • Antimon-Rothgültigerz
  • +19 more

History

Long before anyone could tell two red ores apart, miners in the silver districts of central Europe knew a deep red rock they called Rotgültigerz — ruby silver. The German mining scholar Georg Agricola mentioned it in 1546. But the name covered two different minerals that look almost identical. They were not told apart until chemists analysed both and found one held antimony where the other held arsenic.

The antimony one is pyrargyrite. Its name was coined in 1831 from two Greek words — pyr, fire, and argyros, silver. It means "fire-silver", a nod to both its deep red colour and the silver locked inside it. Large crystals look greyish-black and opaque, but hold a thin sliver to the light and it glows ruby-red.

Its near-twin is proustite, the arsenic version of the same mineral — "light red silver ore" to pyrargyrite's "dark red silver ore". The two share the same crystal form yet rarely blend. The quickest way to separate them is the streak, the colour of the powder a mineral leaves when scraped. Pyrargyrite streaks purplish-red; proustite streaks a brighter scarlet.

The finest crystals came from the old silver-mining heartlands — Sankt Andreasberg in the Harz mountains, Freiberg in Saxony, and Guanajuato in Mexico. Spanish mines at Guadalcanal and Hiendelaencina yielded specimens of unusual quality. In the United States the mineral turned up at Silver City in Idaho and was abundant at the Comstock Lode in Nevada.

Industrial & practical applications

Pyrargyrite is mined for one thing: the silver bound up inside it. The mineral is a source of silver, not of the antimony it also contains. Where it occurs in quantity, smelters recover the silver and leave the antimony aside.

Today that role is small. Pyrargyrite turns up in scattered amounts in silver veins rather than in the massive deposits that feed modern silver supply — it is common in only small amounts even in the silver mines of the western United States. The metal the world uses for coins, electronics and solar cells comes mostly from other, more abundant silver minerals and from the refining of lead, zinc and copper ores.

What demand the mineral still draws is mostly from collectors. Well-formed crystals — dark and metallic in bulk, glowing deep ruby-red where light passes through a thin edge — are sought as display specimens, especially the prized old-locality material from Sankt Andreasberg, Freiberg and Guanajuato.

Where it forms, where it's found

Geological setting

Hydrothermal veins as a late stage, low-temperature mineral; also formed by secondary processes.

1,460recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Sub Metallic
Transparency
Translucent
Colour
Deep red or red gray
Streak
Purplish red
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (1011) very imperfect on (0112)

Fracture
Irregular/Uneven · Conchoidal
Density
5.82 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.881 – 3.084
Surface relief
Very high
Principal indices
nω 3.084 · nε 2.881
Pleochroism
Weak
Anisotropism
Strong in yellow white and grey blue
Tropism
Anisotropic
Reflectance R%
(35.0,41.0) 400, (34.8,40.8) 420, (34.6,40.6) 440, (34.0,40.2) 460, (32.8,39.5) 480, (31.0,37.4) 500, (29.6,35.4) 520, (28.2,34.0) 540, (27.2,32.7) 560, (26.4,31.7) 580, (25.6,30.9) 600, (25.0,30.2) 620, (24.4,29.6) 640, (23.8,29.0) 660, (23.4,28.5) 680, (22.9,28.1) 700
Luminescence
None
Reflected-light panel
28.7 %anisotropic · dual curve
Specimen sRGB 181, 134, 84
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong in yellow white and grey blue

Crystallography

Crystal system
Trigonal
Space group
#85
Cell parameters
a = 11.047 Å · c = 8.719 Å
Z
6
Morphology

Prismatic crystals

Twinning

On (1014), less commonly on (1011) (1120), rarely (0120).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver3107.868323.604
59.76%
51SbAntimonyAntimony1121.760121.760
22.48%
16SSulfurSulfur332.06096.180
17.76%
Total541.544100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As

Synonyms

  • Aerosit
  • Aerosite
  • Antimon-Rothgültigerz
  • Antimonial Red Silver
  • Antimonial Silver Blende
  • Antimonrotgülden
  • Antimonsilberblende
  • Argent antimonié sulfuré
  • Argent rouge antimoniale
  • Argento rosso antimoniale
  • Argyrythrose
  • Dark Red Silver Ore
  • Dunkles Rotgültigerz
  • Gemein Rothguldenerz
  • Mine d'argent rouge
  • Petlanque acerado oscuro
  • Plata roja oscura
  • Pyrargirit
  • Red Silver Ore
  • Rosicler oscuro
  • Rothgolderz
  • Rothgylden

In other languages

French
pyrargyrite
German
Aerosit · Antimonsilberblende · Dunkles Rotgültigerz · Pyrargyrit
Spanish
pirargirita
Italian
pirargirite
Japanese
濃紅銀鉱
Chinese
浓红银矿
Russian
пираргирит

Classification

Strunz
10th ed.

2.GA.05

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GANeso-sulfarsenites, etc. without additional SGroup
  • 2.GA.05PyrargyriteSpecies
Dana
8th ed.

03.04.01.02

  • 03SulfosaltsClass
  • 03.04ø = 3Type
  • 03.04.01Proustite Group (Ruby Silver)Group
  • 03.04.01.02PyrargyriteSpecies
CIM

5.2.9

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.9PyrargyriteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
9 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1795Klaproth, M. H. (1795) IX. Untersuchung der Silbererze, Rothgültigerz . In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 1. Rottmann. p.141-145.
  2. 1831Glocker, E.F. (1831) Rothgülben oder Pyrargyrit. in Handbuch der Mineralogie, Ben Johann Leonhard Schrag (Nürnberg), 388-392.
  3. 1888Miers, H. A. (1888) Contributions to the Study of Pyrargyrite and Proustite. Mineralogical Magazine and Journal of the Mineralogical Society, 8 (37) 37-102 doi:10.1180/minmag.1888.008.37.01 DOI: 10.1180/minmag.1888.008.37.01
  4. 1934Athanasiu, G. (1934) L'effet photoélectrique de quelques cristaux semiconducteurs - II. proustite, pyrargyrite, bournonite, molybdénite. Journal de Physique et le Radium, 5 (3). 132-140 doi:10.1051/jphysrad:0193400503013200DOI: 10.1051/jphysrad:0193400503013200
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pyrargyrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pyrargyrite-3313},
  note      = {Accessed 2026-05-11}
}