Bradaczekite

NaCuCuCu2(AsO4)3
IMA status
  • Approved
IMA symbol
Bdc
IMA approved
2000
Also known as
  • Bradaczekiet
  • IMA2000-002

Where it forms, where it's found

Geological setting

In a <G>fumarole</G>

Type locality
Second scoria cone
  1. Northern Breakthrough (North Breach)
  2. Great Fissure eruption (Main Fracture)
  3. Tolbachik Volcanic field
  4. Milkovsky District
  5. Kamchatka Krai
  6. Russia

55.6878°, 160.2435°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Lustre
Adamantine
Transparency
Transparent
Colour
Dark blue
Streak
Light blue to white
Cleavage
None Observed

Optical

Optical type
Biaxial (-)
Refractive index
1.76 – 1.96
Surface relief
Very high
Principal indices
nα 1.76 · nβ 1.92 · nγ 1.96
Pleochroism
Strong

X = violet-red; Y = green; Z = greenish blue.

Dispersion
r > v
Extinction
Z = b; X ∧ c = 23° in the obtuse β angle.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.2000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2000 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2000 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 12.051 Å · b = 12.434 Å · c = 7.2662 Å
Cell angles
β = 117.942 °
Ratio a:b:c
1 : 1.032 : 0.603
Unit cell volume
961.8 ų
Z
4
Morphology

Plates elongate along [_102]. The well-developed forms are (010), (311), (111) and (112). The forms (301), (001), (321), (101), (100), (021), (110), (131), (111) and (341) are common.

Type-locality form

Aggregates of elongate plates and intergrowths with urusovite and johillerite. Individual grains are about 0.2 mm in length and about 0.1-0.2 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
36.63%
33AsArsenicArsenic374.922224.766
32.39%
8OOxygenOxygen1215.999191.988
27.67%
11NaSodiumSodium122.99022.990
3.31%
Total693.928100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bradaczekiet
  • IMA2000-002

In other languages

French
bradaczekite
German
Bradaczekit · IMA 2000-002
Italian
bradaczekite

Classification

Strunz
10th ed.

8.AC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.10BradaczekiteSpecies
Dana
8th ed.

38.02.04.04

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.04Alluaudite-Wyllieite Group (Wyllieite Subgroup)Group
  • 38.02.04.04BradaczekiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1987Pertlik, F. (1987) Hydrothermal synthesis and structure of sodium tetracopper (II) triarsenate(V). Acta Crystallographica, C43, 381-383. (synthetic)
  2. 2001Krivovichev, S.V., Filatov, S.K., Burns, P.C. (2001) The Jahn-Teller distortion of copper coordination polyhedra in the alluaudite structural type: Crystal structure of bradaczekite, NaCu4(AsO4)3. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 130(5): 1-8.
  3. 2001Filatov, S. K., Vergasova, L. P., Gorskaya, M. G., Krivovichev, S. V., Burns, P. C., Ananiev, V. V. (2001) Bradaczekite, NaCu4(AsO4)3, a new mineral species from the Tolbachik Volcano, Kamchatka Peninsula, Russia. The Canadian Mineralogist, 39 (4) 1115-1119 doi:10.2113/gscanmin.39.4.1115 DOI: 10.2113/gscanmin.39.4.1115
  4. 2001Mandarino, Joseph A. (2001) New minerals. The Canadian Mineralogist, 39 (6) 1751-1760 doi:10.2113/gscanmin.39.6.1751 DOI: 10.2113/gscanmin.39.6.1751
  5. 2002Jambor, J.L., Roberts, A.C. (2002) New mineral names. American Mineralogist: 87: 765-768.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bradaczekite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bradaczekite-10382},
  note      = {Accessed 2026-05-11}
}