Calciojohillerite

NaCaMgMg2(AsO4)3
IMA status
  • Approved
IMA symbol
Cjhl
IMA approved
2016
Also known as
  • Calciojohilleriet
  • IMA2016-068

Where it forms, where it's found

Geological setting

Fumarole

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · pale green · pale yellow · light blue · pale lilac or pink
Tenacity
brittle
Cleavage
Imperfect/Fair
Density
3.915 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 15 – 10°
Refractive index
1.719 – 1.732
Surface relief
High
Principal indices
nα 1.719 · nβ 1.732 · nγ 1.732
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 11.8405(3) Å · b = 12.7836(2) Å · c = 6.6916(2) Å
Cell angles
β = 112.425(3) °
Ratio a:b:c
1 : 1.080 : 0.565
Unit cell volume
936.29 ų
Z
4
Type-locality form

Prismatic crystals up to 1 cm long, their aggregates and crystal crusts up to 0.5 m2.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic374.922224.766
40.67%
8OOxygenOxygen1215.999191.988
34.73%
12MgMagnesiumMagnesium324.30572.915
13.19%
20CaCalciumCalcium140.07840.078
7.25%
11NaSodiumSodium122.99022.990
4.16%
Total552.737100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calciojohilleriet
  • IMA2016-068

In other languages

German
Calciojohillerit · IMA 2016-068

Classification

Strunz
10th ed.

8.AC.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.05CalciojohilleriteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2008Haj Abdallah, Anissa; Haddad, Amor (2008) The alluaudite-like arsenate NaCaMg3(AsO4)3. Acta Crystallographica Section E Structure Reports Online, 64 (6). i36 doi:10.1107/s1600536808014633DOI: 10.1107/s1600536808014633
  2. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter No 34. Mineralogical Magazine, 80 (7) 1315-1321 doi:10.1180/minmag.2016.080.086DOI: 10.1180/minmag.2016.080.086
  3. 2021Pekov, Igor V., Koshlyakova, Natalia N., Agakhanov, Atali A., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2021) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XV. Calciojohillerite, NaCaMgMg2(AsO4)3, a member of the alluaudite group. Mineralogical Magazine, 85 (2) 215-223 doi:10.1180/mgm.2021.2DOI: 10.1180/mgm.2021.2
  4. 2022(2022) Calciojohillerite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2025Mauro, Daniela; Sejkora, Jiří; Dolníček, Zdeněk (2025) Badalovite, NaNaMg(MgFe3+)(AsO4)3, and associated calciojohillerite, NaCaMgMg2(AsO4)3, from Biancavilla, Etna volcanic complex, Sicily, Italy: occurrence and crystal chemistry. Mineralogical Magazine, 89 (4). 526-534 doi:10.1180/mgm.2025.8DOI: 10.1180/mgm.2025.8
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calciojohillerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calciojohillerite-50776},
  note      = {Accessed 2026-05-11}
}