Caryinite

NaCaCaMn2(AsO4)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cyn
Discovered
1874
Also known as
  • Caryiniet
  • Caryinit
  • Karyinite

Where it forms, where it's found

Geological setting

Veinlets in a skarn in a Mn-Fe metamorphosed orebody.

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

6recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Brown to yellowish brown · light yellow-brown in transmitted light.
Streak
Light brown
Tenacity
brittle
Cleavage
Distinct/Good

Distinct on (110) and (010); (110) ^ (110) ~49°15'.

Fracture
Irregular/Uneven
Density
4.29 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38 – 44° · 2V calc = 46°
Refractive index
1.776 – 1.805
Surface relief
High
Principal indices
nα 1.776 · nβ 1.780 · nγ 1.805
Birefringence
0.029
Pleochroism
Non-pleochroic
Dispersion
r > v slight
Extinction
XYZ = cab
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0290
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]290 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation290 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 6.855(2) Å · b = 13.147(3) Å · c = 11.479(4) Å
Cell angles
β = 98.97(2) °
Ratio a:b:c
1 : 1.918 : 1.675
Z
4
Morphology

Cleavable masses, fine grained massive and veins to 10cm.

Comment

Non-standard space-group setting I2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic374.922224.766
35.69%
8OOxygenOxygen1215.999191.988
30.48%
25MnManganeseManganese254.938109.876
17.45%
20CaCalciumCalcium240.07880.156
12.73%
11NaSodiumSodium122.99022.990
3.65%
Total629.776100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Caryiniet
  • Caryinit
  • Karyinite

In other languages

German
Karyinit
Italian
caryinite

Classification

Strunz
10th ed.

8.AC.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.10CaryiniteSpecies
Dana
8th ed.

38.02.02.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.02Alluaudite-Wyllieite Group (Alluaudite Subgroup)Group
  • 38.02.02.01CaryiniteSpecies
CIM

20.5.9

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.5Arsenates of Ti and PbGroup
  • 20.5.9CaryiniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1874Lundström, C. H. (1874) Karyinit från Långbanshyttan i Vermland [Caryinite from Långbanshyttan in Vermland]. Geologiska Föreningen i Stockholm Förhandlingar, 2 (6). 178 doi:10.1080/11035897409448656DOI: 10.1080/11035897409448656
  2. 1881Des Cloizeaux, Alfred (1881) Sur la Roscoelite, la karyinite et la monazite. Bulletin de Minéralogie, 4 (3) 56-58 doi:10.3406/bulmi.1881.1627DOI: 10.3406/bulmi.1881.1627
  3. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  4. 1895Sjögren (1895) Bull. Geol. Inst. Upsala: 2: 87.
  5. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Caryinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/caryinite-912},
  note      = {Accessed 2026-05-11}
}