Bulgakite

Li2(Ca,Na)Fe2+7Ti2(Si4O12)2O2(OH)4(O,F)(H2O)2
IMA status
  • Approved
IMA symbol
Bgk
IMA approved
2014
Also known as
  • Bulgakiet
  • IMA2014-041

Where it forms, where it's found

Geological setting

Fenitized amphibole–quartz–feldspar rock from a glacial morraine

Type locality
Dara-i-Pioz Massif
  1. Districts of Republican Subordination
  2. Tajikistan

39.4504°, 70.7163°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Brownish orange
Streak
pale brown streak
Tenacity
brittle
Cleavage
Perfect

Perfect parallel to (001) and moderate parallel to (010)

Fracture
Hackly
Density
3.30 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 67°
Refractive index
1.695 – 1.75
Surface relief
High
Principal indices
nα 1.695 · nβ 1.711 · nγ 1.750
Pleochroism
Visible

X = intensive reddish brown, Y = light brown, Z = greenish light brown

Dispersion
Strong: r > v
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0550
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]550 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation550 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.374(1) Å · b = 11.965(2) Å · c = 11.654(3) Å
Cell angles
α = 113.457(8) ° · β = 94.533(8) ° · γ = 103.084(10) °
Ratio a:b:c
1 : 2.226 : 2.169
Unit cell volume
657.5 ų
Z
1
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3315.999527.967
39.30%
26FeIronIron755.845390.915
29.10%
14SiSiliconSilicon828.085224.680
16.73%
22TiTitaniumTitanium247.86795.734
7.13%
20CaCalciumCalcium140.07840.078
2.98%
11NaSodiumSodium122.99022.990
1.71%
9FFluorineFluorine118.99818.998
1.42%
3LiLithiumLithium26.94013.880
1.03%
1HHydrogenHydrogen81.0088.064
0.60%
Total1343.306100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bulgakiet
  • IMA2014-041

In other languages

German
Bulgakit · IMA 2014-041
Italian
bulgakite

Classification

Strunz
10th ed.

9.DC

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DCInosilicates with branched 2-periodic single chains; Si2O6 + 2SiO3 Si4O12Group
  • 9.DCBulgakiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), CNMNC Newsletter No. 22. Mineralogical Magazine, 78 (5) 1241-1248 doi:10.1180/minmag.2014.078.5.10DOI: 10.1180/minmag.2014.078.5.10
  2. 2016Agakhanov, Atali A., Pautov, Leonid A., Sokolova, Elena, Abdu, Yassir A., Karpenko, Vladimir Y. (2016) Two Astrophyllite-Supergroup Minerals: Bulgakite, A New Mineral From the Darai-Pioz Alkaline Massif, Tajikistan and Revision of the Crystal Structure and Chemical Formula of Nalivkinite. The Canadian Mineralogist, 54 (1) 33-48 doi:10.3749/canmin.1500085 DOI: 10.3749/canmin.1500085
  3. 2017(2017) Bulgakite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bulgakite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bulgakite-46415},
  note      = {Accessed 2026-05-11}
}