Nalivkinite

Li2NaFe2+7Ti2(Si4O12)2O2(OH)4F(H2O)2
IMA status
  • Approved
IMA symbol
Nlv
IMA approved
2006
Also known as
  • IMA2006-038
  • Nalivkiniet

Where it forms, where it's found

Type locality
Dara-i-Pioz Massif
  1. Districts of Republican Subordination
  2. Tajikistan

39.4504°, 70.7163°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Brown with a bronze hue
Density
3.32 g/cm³

Optical

Optical type
· 2V calc = 68.6°

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.3745(6) Å · b = 11.9299(15) Å · c = 11.6509(4) Å
Cell angles
α = 113.325 ° · β = 94.524 ° · γ = 103.08 °
Ratio a:b:c
1 : 2.220 : 2.168
Unit cell volume
656.2 ų
Z
1
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3215.999511.968
39.77%
26FeIronIron755.845390.915
30.37%
14SiSiliconSilicon828.085224.680
17.45%
22TiTitaniumTitanium247.86795.734
7.44%
11NaSodiumSodium122.99022.990
1.79%
9FFluorineFluorine118.99818.998
1.47%
3LiLithiumLithium26.94013.880
1.08%
1HHydrogenHydrogen81.0088.064
0.63%
Total1287.229100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2006-038
  • Nalivkiniet

In other languages

German
IMA 2006-038 · Nalivkinit
Italian
nalivkinite

Classification

Strunz
10th ed.

9.DC.05

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DCInosilicates with branched 2-periodic single chains; Si2O6 + 2SiO3 Si4O12Group
  • 9.DC.05NalivkiniteSpecies
Dana
8th ed.

69.01.01.05

  • 69Inosilicates Chains with Side Branches or LoopsClass
  • 69.01Chains with Side Branches or Loops with (P=2, and N=4, 2 branches)Type
  • 69.01.01Astrophyllite groupGroup
  • 69.01.01.05NalivkiniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2008Agakhanov, A. A., Pautov, L. A., Uvarova, Y. A., Sokolova, E., Hawthorne, F. C., Karpenko, V. Y. (2008) Nalivkinite, Li2NaFe2+7Ti2(Si8O24)O2(OH)4F, a new mineral of the astrophyllite group from the Darai-Pioz Massif, Tadjikistan. New Data on Minerals, 43. Moscow. 5-12
  2. 2008Uvarova, Y. A., Sokolova, E., Hawthorne, F. C., Agakhanov, A. A., Pautov, L. A. (2008) The crystal structure of nalivkinite, a new lithium member of the astrophyllite group. The Canadian Mineralogist, 46 (3) 651-659 doi:10.3749/canmin.46.3.651 DOI: 10.3749/canmin.46.3.651
  3. 2010Cámara, Fernando; Sokolova, Elena; Abdu, Yassir; Hawthorne, Frank C. (2010) The crystal structures of niobophyllite, kupletskite-(Cs) and Sn-rich astrophyllite: revisions to the crystal chemistry of the astrophyllite-group minerals. The Canadian Mineralogist, 48 (1). 1-16 doi:10.3749/canmin.48.1.1 DOI: 10.3749/canmin.48.1.1
  4. 2012Sokolova, E. (2012) Further developments in the structure topology of the astrophyllite-group minerals. Mineralogical Magazine, 76 (4) 863-882 doi:10.1180/minmag.2012.076.4.04 DOI: 10.1180/minmag.2012.076.4.04
  5. 2016Agakhanov, Atali A., Pautov, Leonid A., Sokolova, Elena, Abdu, Yassir A., Karpenko, Vladimir Y. (2016) Two Astrophyllite-Supergroup Minerals: Bulgakite, A New Mineral From the Darai-Pioz Alkaline Massif, Tajikistan and Revision of the Crystal Structure and Chemical Formula of Nalivkinite. The Canadian Mineralogist, 54 (1) 33-48 doi:10.3749/canmin.1500085 DOI: 10.3749/canmin.1500085
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nalivkinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nalivkinite-31307},
  note      = {Accessed 2026-05-11}
}