Niobophyllite

K2NaFe2+7(Nb,Ti)2(Si4O12)2O2(OH)4(O,F)
IMA status
  • Approved
IMA symbol
Nbp
Discovered
1964
Also known as
  • IMA1964-001
  • Niobophylliet
  • Niobophyllita

Where it forms, where it's found

Geological setting

Alkaline syenite.

Type locality
Mann 2 (Ten Mile Lake)
  1. Seal Lake alkaline complex (Letitia Lake)
  2. Labrador
  3. Newfoundland and Labrador
  4. Canada

54.2000°, -62.5000°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Chocolate-brown
Cleavage
Perfect

Perfect on (001), poor on {0kl}

Density
3.42 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60° · 2V calc = 58°
Refractive index
1.724 – 1.772
Surface relief
High
Principal indices
nα 1.724 · nβ 1.760 · nγ 1.772
Pleochroism
Strong

X = Y = brownish yellow; Z = red-orange.

Dispersion
r > v medium
Extinction
Y = a; X ∧ b = 13°; Z ⊥ {001}.
Michel-Lévy diagramhighlighted lineδ = 0.0480
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]480 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation480 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 5.4022(6) Å · b = 11.8844(6) Å · c = 11.6717(6) Å
Cell angles
α = 112.990(1) ° · β = 94.588(1) ° · γ = 103.166(1) °
Ratio a:b:c
1 : 2.200 : 2.161
Z
1
Twinning

By reflection on (001), common.

Type-locality form

Polycrystalline aggregates of small flakes.

Comment

Point Group: _1 or 1; Space Group: P_1 or P1. Cell parameters from Cámara et al. (2010).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3115.999495.969
32.69%
26FeIronIron755.845390.915
25.76%
14SiSiliconSilicon828.085224.680
14.81%
41NbNiobiumNiobium292.906185.812
12.25%
22TiTitaniumTitanium247.86795.734
6.31%
19KPotassiumPotassium239.09878.196
5.15%
11NaSodiumSodium122.99022.990
1.51%
9FFluorineFluorine118.99818.998
1.25%
1HHydrogenHydrogen41.0084.032
0.27%
Total1517.326100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Ta
  • Mg
  • Ca
  • H2O

Synonyms

  • IMA1964-001
  • Niobophylliet
  • Niobophyllita

In other languages

German
IMA 1964-001 · Niobophyllit
Italian
Niobofillite · Niobophyllite

Classification

Strunz
10th ed.

9.DC.05

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DCInosilicates with branched 2-periodic single chains; Si2O6 + 2SiO3 Si4O12Group
  • 9.DC.05NiobophylliteSpecies
Dana
8th ed.

69.01.01.04

  • 69Inosilicates Chains with Side Branches or LoopsClass
  • 69.01Chains with Side Branches or Loops with (P=2, and N=4, 2 branches)Type
  • 69.01.01Astrophyllite groupGroup
  • 69.01.01.04NiobophylliteSpecies
CIM

17.8.17

  • 17Silicates Containing other AnionsClass
  • 17.8Silicates with niobate or tantalateGroup
  • 17.8.17NiobophylliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1964Nickel, E. H., Rowland, J. F., Charette, D. J. (1964) Niobophyllite - the niobium analogue of astrophyllite; a new mineral from Seal Lake, Labrador. The Canadian Mineralogist, 8 (1) 40-52
  2. 1965Fleischer, Michael (1965) New Mineral Names. American Mineralogist, 50 (1-2) 261-268
  3. 2001(2001) Niobophyllite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2003Demartin, Francesco; Guastoni, Alessandro; Pezzotta, Federico (2003) Barylith, Niobophyllit & yttriumreicher Milarit - Neufunde aus den Pegmatiten von Zomba-Malosa, Malawi [Barylite, niobophyllite & yttrium-rich milarite - new finds from the pegmatites of Zomba-Malosa, Malawi]. Lapis, 28 (1). 18-21; 58
  5. 2010Cámara, Fernando; Sokolova, Elena; Abdu, Yassir; Hawthorne, Frank C. (2010) The crystal structures of niobophyllite, kupletskite-(Cs) and Sn-rich astrophyllite: revisions to the crystal chemistry of the astrophyllite-group minerals. The Canadian Mineralogist, 48 (1). 1-16 doi:10.3749/canmin.48.1.1 DOI: 10.3749/canmin.48.1.1
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Niobophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/niobophyllite-2911},
  note      = {Accessed 2026-05-11}
}