Caracolite

Na2(Pb2Na)(SO4)3Cl
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cco
Discovered
1886
Also known as
  • Caracoliet

Where it forms, where it's found

Geological setting

In Ash from lead smelters.

Type locality
Beatriz Mine
  1. Caracoles
  2. Caracoles mining district
  3. Sierra Gorda
  4. Antofagasta Province
  5. Antofagasta
  6. Chile

-22.9578°, -69.0769°

21recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · grayish · greenish stained · colourless in transmitted light.
Cleavage
None Observed
Density
5.1 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.743 – 1.764
Surface relief
High
Principal indices
nα 1.743 · nβ 1.754 · nγ 1.764
Dispersion
r > v moderate
Notes

2V(meas.) = Very large.

Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 19.62 Å · b = 7.14 Å · c = 9.81 Å
Cell angles
β = 120 °
Ratio a:b:c
1 : 0.364 : 0.500
Z
4
Morphology

Occurs as crystalline incrustations. Imperfect crystals to 1 mm apparently hexagonal with a hexagonal pyramid and prism plus a large base.

Twinning

Pseudo-hexagonal trillings, analogous to aragonite. Exhibits complex polysynthetic twinning with rather large extinction angles.

Type-locality form

Crystalline incrustations with pseudohexagonal crystals to 1mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
51.35%
8OOxygenOxygen1215.999191.988
23.79%
16SSulfurSulfur332.06096.180
11.92%
11NaSodiumSodium322.99068.970
8.55%
17ClChlorineChlorine135.45035.450
4.39%
Total806.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Caracoliet

In other languages

German
Caracolit
Spanish
Caracolita
Italian
Caracolite

Classification

Strunz
10th ed.

7.BD.20

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.20CaracoliteSpecies
Dana
8th ed.

30.03.02.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.03(AB)5(XO4)3ZqType
  • 30.03.02— unnamed intermediate level —Group
  • 30.03.02.01CaracoliteSpecies
CIM

26.25

  • 26Sulphates with HalideClass
  • 26.25— unnamed intermediate level —Group
  • 26.25CaracoliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1886Websky, M. (1886) Über caracolite und percylit. Sitzungsberichte der Königlich Preussischen Akademie der Wissenschaften, Berlin: 48: 1045-1050.
  2. 1889Fletcher, L. (1889) On Crystals of Percylite, Caracolite, and an Oxychloride of Lead (Daviesite), from Mina Beatriz, Sierra Gorda, Atacama, South America. Mineralogical Magazine, 8 (39) 171-180 doi:10.1180/minmag.1889.008.39.01 DOI: 10.1180/minmag.1889.008.39.01
  3. 1913(1913) Atlas Der Krystallformen Vol. 2 - Text - Band II - Calaverit-Cyanochroit. Carl Winters Universitätsbuchhandlung, Heidelberg.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Caracolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/caracolite-890},
  note      = {Accessed 2026-05-11}
}