Cesanite

Ca2Na3(SO4)3OH
IMA status
  • Approved
IMA symbol
Csa
Discovered
1981
Also known as
  • Cesaniet
  • IMA1980-023

Where it forms, where it's found

Geological setting

Core sample from a geothermal well in volcanic and pyroclastic rocks.

Type locality
Cesano 1 well
  1. Cesano geothermal field
  2. Metropolitan City of Rome Capital
  3. Lazio
  4. Italy

42.1000°, 12.3551°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · white
Streak
White
Cleavage
Very Good

Pronounced, normal to the elongation.

Density
2.786 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.564 – 1.57
Surface relief
Moderate
Principal indices
nω 1.570 · nε 1.564
Pleochroism
Non-pleochroic
Notes

Negative elongation.

Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#100
Cell parameters
a = 9.4630(8) Å · c = 6.9088(5) Å
Z
1
Morphology

Short prismatic, hexagonal shaped, with a length to diameter ratio between 2:1 and 4:1. Striations on the prism faces. Forms include the prism (1010), pyramid (1011), pinacoid (0001), and another pyramid {10_1l}.

Twinning

Occassional twins accoridng to (1010).

Type-locality form

A solid vein, 1 cm thick. Also as a cavity-filling in an explosive breccia. The vein has a sugary texture and grain size ranging from 0.2 to 1.5 mm. Individual crystals, mostly subhedral and loosely packed, can be easily removed.

Comment

P-6 according to Piotrowski et al. (2002). Originally assumed to be P63/m.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
45.78%
16SSulfurSulfur332.06096.180
21.17%
20CaCalciumCalcium240.07880.156
17.65%
11NaSodiumSodium322.99068.970
15.18%
1HHydrogenHydrogen11.0081.008
0.22%
Total454.301100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cesaniet
  • IMA1980-023

In other languages

German
Cesanit · IMA 1980-023
Italian
cesanite

Classification

Strunz
10th ed.

7.BD.20

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.20CesaniteSpecies
Dana
8th ed.

30.03.03.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.03(AB)5(XO4)3ZqType
  • 30.03.03— unnamed intermediate level —Group
  • 30.03.03.01CesaniteSpecies
CIM

25.4.5

  • 25SulphatesClass
  • 25.4Sulphates of Ca, Sr and BaGroup
  • 25.4.5CesaniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1981Cavarretta, G.; Mottana, A.; Tecce, F. (1981) Cesanite, Ca2Na3[(OH)(SO4)3], a sulphate isotypic to apatite, from the Cesano geothermal field (Latium, Italy). Mineralogical Magazine, 44 (335). 269-273 doi:10.1180/minmag.1981.044.335.05 DOI: 10.1180/minmag.1981.044.335.05
  2. 1982Fleischer, M., Cabri, L.J., Chao, G.Y., Mandarino, J.A., Pabst, A. (1982) New mineral names. American Mineralogist: 67: 621-624.
  3. 1983Deganello, S. (1983): The crystal structure of cesanite at 21 and 236 °C. Neues Jahrbuch für Mineralogie, Monatshefte, 1983, 305-313.
  4. 1983Tazzoli, V. (1983) The crystal structure of cesanite, Ca1+xNa4−x(SO4)3(OH)x · (1−x)H2O, a sulphate isotypic to apatite. Mineralogical Magazine, 47 (342). 59-63 doi:10.1180/minmag.1983.047.342.10 DOI: 10.1180/minmag.1983.047.342.10
  5. 1984Deganello, S. (1984): The crystal structure of cesanite at 336 and 390°C. Neues Jahrbuch für Mineralogie, Monatshefte, 1984, 522-528.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cesanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cesanite-938},
  note      = {Accessed 2026-05-11}
}