Phosphohedyphane

Ca2Pb3(PO4)3Cl
IMA status
  • Approved
IMA symbol
Phdy
IMA approved
2005
Also known as
  • IMA2005-026
  • Phosphohedyphaan
  • Polysphaerite

Where it forms, where it's found

Geological setting

Secondary mineral in the oxidized zone of a Cu-Pb-Ag deposit.

Type locality
Capitana Mine
  1. Copiapó
  2. Copiapó Province
  3. Atacama
  4. Chile

-27.3639°, -70.1456°

100recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Sub-Conchoidal
Density
5.92 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.928 – 1.935
Surface relief
Very high
Principal indices
nω 1.935 · nε 1.928
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#108
Cell parameters
a = 9.857 Å · c = 7.13 Å
Unit cell volume
599.9 ų
Z
2
Morphology

Forms observed are (100) and (101) good, (411) poor, and {10.0.1} and {20.0.1} (approx.)

Type-locality form

Transparent, colourless, tapering hexagonal prisms, as individuals up to about 0.5 mm in length and 0.1 mm in diameter, commonly doubly terminated; often in subparallel intergrowths and irregular clusters.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
60.82%
8OOxygenOxygen1215.999191.988
18.78%
15PPhosphorusPhosphorus330.97492.922
9.09%
20CaCalciumCalcium240.07880.156
7.84%
17ClChlorineChlorine135.45035.450
3.47%
Total1022.116100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-026
  • Phosphohedyphaan
  • Polysphaerite

In other languages

French
Calcium-pyromorphite · Nussièrite · Phosphohedyphane · Polysphaerite
German
IMA 2005-026 · Phosphohedyphan
Italian
fosfohedyphane · nussièrite · polysphaerite

Classification

Strunz
10th ed.

8.BN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
  • 8.BN.05PhosphohedyphaneSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2006Kampf, A. R., Steele, I. M., Jenkins, R. A. (2006) Phosphohedyphane, Ca2Pb3(PO4)3Cl, the phosphate analog of hedyphane: Description and crystal structure. American Mineralogist, 91 (11) 1909-1917 doi:10.2138/am.2006.2268 DOI: 10.2138/am.2006.2268
  2. 2007Birch, W. D. & Mills, S. J. (2007) Sulphide–carbonate reaction in recrystallised limestone at Lilydale, Victoria, Australia: a new occurrence of phosphohedyphane, Australian Journal of Mineralogy, 13(2), 73–82.
  3. 2014Frost, Ray L., Scholz, Ricardo, López, Andrés, Firmino, Bárbara E., Lana, Cristiano, Xi, Yunfei (2014) A Raman and infrared spectroscopic characterisation of the phosphate mineral phosphohedyphane Ca2Pb3(PO4)3Cl from the Roote mine, Nevada, USA. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 127. 237-242 doi:10.1016/j.saa.2014.02.067DOI: 10.1016/j.saa.2014.02.067
  4. 2022(2022) Phosphohedyphane. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphohedyphane — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphohedyphane-27608},
  note      = {Accessed 2026-05-11}
}