Where it forms, where it's found
- Geological setting
Secondary mineral in the oxidized zone of a Cu-Pb-Ag deposit.
- Type locality
- Capitana Mine
- Copiapó
- Copiapó Province
- Atacama
- Chile
-27.3639°, -70.1456°
Safety & handling
Physical
Optical
- Optical type
- Uniaxial (-)
- Refractive index
- 1.928 – 1.935
- Surface relief
- Very high
- Principal indices
- nω 1.935 · nε 1.928
- UV response
- Not fluorescent.
Crystallography
- Space group
- #108
- Cell parameters
- a = 9.857 Å · c = 7.13 Å
- Unit cell volume
- 599.9 ų
- Z
- 2
- Morphology
Forms observed are (100) and (101) good, (411) poor, and {10.0.1} and {20.0.1} (approx.)
- Type-locality form
Transparent, colourless, tapering hexagonal prisms, as individuals up to about 0.5 mm in length and 0.1 mm in diameter, commonly doubly terminated; often in subparallel intergrowths and irregular clusters.
Chemical composition
Synonyms
- IMA2005-026
- Phosphohedyphaan
- Polysphaerite
In other languages
- French
- Calcium-pyromorphite · Nussièrite · Phosphohedyphane · Polysphaerite
- German
- IMA 2005-026 · Phosphohedyphan
- Italian
- fosfohedyphane · nussièrite · polysphaerite
Classification
8.BN.05
- 8Phosphates, Arsenates, VanadatesClass
- 8.BPhosphates, etc., with additional anions, without H2ODivision
- 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
- 8.BN.05PhosphohedyphaneSpecies
Group, growth & confusion
AiolositeNa2(Na2Bi)(SO4)3ClMineral—
CaracoliteNa2(Pb2Na)(SO4)3ClMineral—
CesaniteCa2Na3(SO4)3OHMineral—- FluorphosphohedyphaneCa2Pb3(PO4)3FMineral—
- FluorsigaiiteCa2Sr3(PO4)3FMineral—
HedyphaneCa2Pb3(AsO4)3ClMineral—- HydroxylhedyphaneCa2Pb3(AsO4)3(OH)Mineral—
Miyahisaite(Sr,Ca)2Ba3(PO4)3FMineral—
MorelanditeCa2Ba3(AsO4)3ClMineral—- ParafiniukiteCa2Mn3(PO4)3ClMineral—
Literature, links & citation
- 2006Kampf, A. R., Steele, I. M., Jenkins, R. A. (2006) Phosphohedyphane, Ca2Pb3(PO4)3Cl, the phosphate analog of hedyphane: Description and crystal structure. American Mineralogist, 91 (11) 1909-1917 doi:10.2138/am.2006.2268 DOI: 10.2138/am.2006.2268
- 2007Birch, W. D. & Mills, S. J. (2007) Sulphide–carbonate reaction in recrystallised limestone at Lilydale, Victoria, Australia: a new occurrence of phosphohedyphane, Australian Journal of Mineralogy, 13(2), 73–82.
- 2014Frost, Ray L., Scholz, Ricardo, López, Andrés, Firmino, Bárbara E., Lana, Cristiano, Xi, Yunfei (2014) A Raman and infrared spectroscopic characterisation of the phosphate mineral phosphohedyphane Ca2Pb3(PO4)3Cl from the Roote mine, Nevada, USA. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 127. 237-242 doi:10.1016/j.saa.2014.02.067DOI: 10.1016/j.saa.2014.02.067
- 2022(2022) Phosphohedyphane. Handbook of Mineralogy. Mineralogical Society of America
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Phosphohedyphane — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/phosphohedyphane-27608},
note = {Accessed 2026-05-11}
}