Carnallite

KMgCl3 · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cna
Discovered
1856
Also known as
  • Kalium Magnesium chlorid

Where it forms, where it's found

Geological setting

Upper layers of saline deposits of the marine type.

Saline marine deposits by action of high potash fluids.

Type locality
Staßfurt
  1. Salzlandkreis
  2. Saxony-Anhalt
  3. Germany

51.8531°, 11.5883°

124recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow to white · reddish · seldom white · colourless or blue.
Streak
White
Cleavage
None Observed
Fracture
Conchoidal
Density
1.602 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 66°
Refractive index
1.465 – 1.496
Surface relief
Low
Principal indices
nα 1.465 – 1.466 · nβ 1.474 – 1.475 · nγ 1.494 – 1.496
Dispersion
r < v
UV response
None.
Michel-Lévy diagramhighlighted lineδ = 0.0295
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]295 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation295 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#72
Cell parameters
a = 16.119(3) Å · b = 22.472(4) Å · c = 9.551(2) Å
Ratio a:b:c
1 : 1.394 : 0.593
Z
12
Morphology

Crystals pseudo-hexagonal, pyramidal in habit, due to the substantially equant development of pyramids and brachydomes. Thick tabular with large (0001) at times. Massive, granular.

Twinning

Secondary twinning lamellae. May exhibit polysynthetic twinning.

Epitaxy

Hematite scales oriented with (0001) parallel to carnallite (001), also parallel (110) or (100).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine335.450106.350
38.28%
8OOxygenOxygen615.99995.994
34.55%
19KPotassiumPotassium139.09839.098
14.07%
12MgMagnesiumMagnesium124.30524.305
8.75%
1HHydrogenHydrogen121.00812.096
4.35%
Total277.843100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Br
  • Rb
  • Cs
  • Tl
  • Fe

Synonyms

  • Kalium Magnesium chlorid

In other languages

French
carnallite
German
Carnallit
Spanish
carnalita
Italian
carnallite
Portuguese
carnallita · carnallite
Japanese
カーナライト · カーナル石
Chinese
光卤石 · 光鹵石
Simplified Chinese
光卤石
Traditional Chinese
光鹵石
Russian
карналлит
Arabic
كارناليت

Classification

Strunz
10th ed.

3.BA.10

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BAM:X = 1:1 and 2:3Group
  • 3.BA.10CarnalliteSpecies
Dana
8th ed.

11.01.02.01

  • 11Halide ComplexesClass
  • 11.01AmBX3Type
  • 11.01.02— unnamed intermediate level —Group
  • 11.01.02.01CarnalliteSpecies
CIM

8.4.5

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.4Halides of the alkaline earths and MgGroup
  • 8.4.5CarnalliteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1856Rose, Heinr. (1856) Ueber den Carnallit. Annalen der Physik und Chemie, 174. 161-163 doi:10.1002/andp.18561740513DOI: 10.1002/andp.18561740513
  2. 1862Erdmann, E. (1862) Vorkommen von Rubidium und Caesium in Carnallit. Journal für praktische Chemie, Leipzig: 86: 377.
  3. 1873Weiss, E. (1873) Über Steinsalz-Pseudomorphosen von Westeregeln. Zeitschrift der Deutschen Geologischen Gesellschaft: 25(3): 552-561.
  4. 1874Kosmann, P. (1874) Über den inneren Bau der Pseudomorphosen von Steinsalz nach Carnallite von Westeregein. Zeitschrift der Deutschen Geologischen Gesellschaft: 26: 364.
  5. 1875Hammerbacher, F. (1875) Über das Vorkommen von Thallium im Carnallit. Annalen der Chemie Pharm.: 176(1): 82-84.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Carnallite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/carnallite-906},
  note      = {Accessed 2026-05-11}
}