Chalcophyllite

Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Chp
Discovered
1841
Also known as
  • Blättriges Olivinerz
  • Chalkophyllite
  • Copper Mica
  • +8 more

Where it forms, where it's found

Geological setting

Oxidised zone of arsenic-bearing polymetallic hydrothermal deposits.

Type locality
Cornwall
  1. England
  2. UK
207recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous to Sub-adamantine
Transparency
Transparent · Translucent
Colour
Emerald green · grass green · bluish green · blue · green in transmitted light
Streak
Pale green to bluish green
Cleavage
Perfect

Perfect on (0001), micaceous; in traces on (1011).

Density
2.67 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.552 – 1.632
Surface relief
Moderate
Principal indices
nω 1.618 – 1.632 · nε 1.552 – 1.575
Pleochroism
Weak

O = Bluish green E = Nearly colourless

Notes

Indices of refraction vary markedly depending on the relative humidity since the water content varies at ambient temperature.

Michel-Lévy diagramhighlighted lineδ = 0.0615
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]615 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation615 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 10.756(2) Å · c = 28.678(4) Å
Morphology

Crystals platy, six-sided with a hexagonal aspect, flattened on (0001), with prominent (0112). May exhibit numerous other forms and may be striated triangularly on (0001); forms rosettes: also drusy, foliated, massive.

Twinning

On (1010) as twin plane.

Comment

Z = 1.5

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen8815.9991407.912
45.44%
29CuCopperCopper1863.5461143.828
36.92%
33AsArsenicArsenic474.922299.688
9.67%
1HHydrogenHydrogen961.00896.768
3.12%
16SSulfurSulfur332.06096.180
3.11%
13AlAluminiumAluminium226.98253.964
1.74%
Total3098.340100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Blättriges Olivinerz
  • Chalkophyllite
  • Copper Mica
  • Cuivre arseniaté lamelliforme
  • Erinite (of Beudant)
  • Euchlore-Mica
  • Euchlorose
  • Kupferglimmer
  • Kupferphyllit
  • Métachalcophyllite
  • Tamarite (of Brooke and Miller)

In other languages

French
Chalcophyllite
German
Chalkophyllit · Kupferglimmer · Kupferphyllit
Spanish
Calcofilita · Chalkophyllita
Italian
Calcofillite
Russian
халькофиллит
Arabic
كالكوفيليت

Classification

Strunz
10th ed.

8.DF.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DFWith only medium-sized cations, (OH,etc.):RO4 > 3:1Group
  • 8.DF.30ChalcophylliteSpecies
Dana
8th ed.

43.05.14.01

  • 43Compound Phosphates, Etc.Class
  • 43.05Hydrated Compound Phosphates, etc·, Containing Hydroxyl or HalogenType
  • 43.05.14— unnamed intermediate level —Group
  • 43.05.14.01ChalcophylliteSpecies
CIM

22.3.6

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.3Phosphates, arsenates or vanadates with sulphatesGroup
  • 22.3.6ChalcophylliteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1801Haüy, René Just (1801) Traité de Minéralogie (1st ed.) Vol. 3. Chez Louis, Paris.
  2. 1801Vauquelin (1801) Journal des mines: 10: 562.
  3. 1801Karsten in Hoffmann, C.A.S. (1801): 1: 543 (as Blättriges Olivinerz).
  4. 1803Ludwig, C.F. (1803) Handbuch der Mineralogie nach A.G. Werner. 2 volumes, Leipzig: 180 (as Kupferglimmer).
  5. 1820Jameson, R. (1820) A System of Mineralogy. third edition, 3 volumes (as Copper Mica).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcophyllite-979},
  note      = {Accessed 2026-05-11}
}