Liroconite

Cu2Al(AsO4)(OH)4 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lro
Also known as
  • Chalcophacit
  • Couphochlorit
  • Couphochlorita
  • +13 more

Where it forms, where it's found

Geological setting

Oxidized zones of copper deposits.

Type locality
Wheal Gorland
  1. St Day
  2. Cornwall
  3. England
  4. UK

50.2417°, -5.1839°

26recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Sky-blue to green · light blue to light bluish green in transmitted light.
Streak
Pale blue to pale green
Cleavage
Poor/Indistinct

On (110) and (011), indistinct.

Fracture
Irregular/Uneven · Conchoidal
Density
2.94 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 67° · 2V calc = 72°
Refractive index
1.612 – 1.675
Surface relief
Moderate
Principal indices
nα 1.612 · nβ 1.652 · nγ 1.675
Pleochroism
Non-pleochroic
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0630
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]630 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation630 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 12.664(2) Å · b = 7.553(2) Å · c = 9.914(3) Å
Cell angles
β = 91.32 °
Ratio a:b:c
1 : 0.596 : 0.783
Z
4
Morphology

Crystals thin or lenticular [001] with a flat octahedral aspect. The faces of m and e are striated parallel to their intersection edges.

Type-locality form

Blue bipyramids

Comment

Space Group: I2/a

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
44.33%
29CuCopperCopper263.546127.092
29.35%
33AsArsenicArsenic174.92274.922
17.30%
13AlAluminiumAluminium126.98226.982
6.23%
1HHydrogenHydrogen121.00812.096
2.79%
Total433.080100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chalcophacit
  • Couphochlorit
  • Couphochlorita
  • Couphochlorite
  • Cuivre Arseniaté Octaèdre obtus
  • Lenticular Copper
  • Lentil-Ore
  • Lentulit
  • Lentulita
  • Lentulite
  • Linsenerz
  • Linsenkupfer
  • Lirocone-Malachite
  • Lirokomalachit
  • Lirokon-malachit
  • Octahedral Arseniate of Copper

In other languages

French
Couphochlorite · Lentulite · Liroconite
German
Linsenerz · Lirokonit
Spanish
Liroconita
Italian
Liroconite

Classification

Strunz
10th ed.

8.DF.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DFWith only medium-sized cations, (OH,etc.):RO4 > 3:1Group
  • 8.DF.20LiroconiteSpecies
Dana
8th ed.

42.02.01.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.02(AB)3(XO4)Zq·xH2OType
  • 42.02.01— unnamed intermediate level —Group
  • 42.02.01.01LiroconiteSpecies
CIM

20.1.13

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.1Arsenates of CuGroup
  • 20.1.13LiroconiteSpecies

Group, growth & confusion

Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1801Bournon, J.L. (1801) Description of the arseniates of copper, and of iron, from the county of Cornwall. Philosophical Transactions: 169-192 (174). (as Octahedral Arseniate of Copper).
  2. 1801Bournon, J.L. (1801) Description of the arseniates of copper, and of iron, from the county of Cornwall. Philosophical Transactions: 169-192 (174).
  3. 1802Rashleigh, P. (1802) Specimens of British Minerals Selected from the Cabinet of Phillip Rashleigh. London. part 2: Pl. 2, 5, 11 (as Octahedral Arseniate of Copper).
  4. 1803Werner (1803) (as Linsenerz).
  5. 1804Werner (1804) Ludwig's Min.: 2: 215 (as Linsenerz).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liroconite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liroconite-2413},
  note      = {Accessed 2026-05-11}
}