Cornwallite

Cu5(AsO4)2(OH)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cnw
Discovered
1846
Also known as
  • Cornwalliet
  • Erinite (of Haidinger)

History

The name points straight at the place it was found. In 1846 the Bohemian mineralogist František Xaver Maximilian Zippe named the mineral after Cornwall, the county in south-west England. Cornwall also holds its type locality — the first place a mineral is ever recorded.

That first occurrence was at Wheal Gorland, one of the workings of the St Day United Mines in the St Day mining district of Cornwall.

Cornwallite is a copper arsenate — a mineral built from copper, arsenic and oxygen. It forms as a secondary mineral, meaning it grows later, as earlier minerals break down rather than crystallising from the original melt or fluid. It appears in the oxidized zone of copper sulfide deposits, the near-surface band where air and water have rotted the primary ore. There it spreads as green radial to fibrous encrustations, thin crusts of needle-like crystals fanning out from a point.

Industrial & practical applications

Cornwallite has no industrial use. It is far too rare for that — an uncommon mineral found as thin green crusts in the weathered tops of a few copper deposits. Where it does turn up, it is of interest to collectors and to mineralogists studying the species, not to industry.

One practical point is worth flagging for anyone who handles a specimen. Cornwallite is a copper arsenate, so each crystal carries arsenic locked into its structure. That makes it a mineral to keep behind glass and to handle with washed hands rather than to grind, lick or breathe as dust.

Where it forms, where it's found

Geological setting

Copper bearing sulfide veins

Found in the oxidized zones of copper deposits.

Type locality
Wheal Gorland
  1. St Day
  2. Cornwall
  3. England
  4. UK

50.2417°, -5.1839°

188recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Verdigis green · blackish-green · emerald-green · emerald-green in transmitted light.
Streak
Apple green
Tenacity
brittle
Cleavage
Distinct/Good

On one direction.

Fracture
Irregular/Uneven · Conchoidal
Density
4.17 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 30 – 50° · 2V calc = 34°
Refractive index
1.81 – 1.88
Surface relief
Very high
Principal indices
nα 1.810 – 1.820 · nβ 1.815 – 1.860 · nγ 1.850 – 1.880
Birefringence
0.050
Dispersion
r > v
UV response
Not Fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 17.33 Å · b = 5.82 Å · c = 4.60 Å
Cell angles
β = 92.22 °
Ratio a:b:c
1 : 0.336 : 0.265
Z
2
Morphology

Microcrystalline, radial fibrous botyroidal to globular and vitreous crusts. Less common as rounded tabular to blocky crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
47.88%
8OOxygenOxygen1215.999191.988
28.93%
33AsArsenicArsenic274.922149.844
22.58%
1HHydrogenHydrogen41.0084.032
0.61%
Total663.594100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cornwalliet
  • Erinite (of Haidinger)

In other languages

French
cornwallite
German
Cornwallit
Spanish
Cornwallita · cornwallite
Italian
Cornwallite
Chinese
水綠砷銅礦
Arabic
كورنواليت

Classification

Strunz
10th ed.

8.BD.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.BD.05CornwalliteSpecies
Dana
8th ed.

41.04.02.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.02— unnamed intermediate level —Group
  • 41.04.02.02CornwalliteSpecies
CIM

20.1.4

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.1Arsenates of CuGroup
  • 20.1.4CornwalliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1828Haidinger, H. (1828) Annalen der Physik, Halle, Leipzig: 14: 228 (as Erinite).
  2. 1828Haidinger, H. (1828) Erinite, a new mineral species. Philosophical Magazine and Journal of Science: 4: 154-155. (as Erinite)
  3. 1847Zippe, F.X.M. (1847) Über den Cornwallit, eine neue Species des Mineralreichs. Abhandlungen der Königlichen Böhmischen Gesellschaft der Wissenschaften: 4: 649-654.
  4. 1858Greg, Robert Philips, Lettsom, William G. (1858) Manual of the Mineralogy of Great Britain and Ireland. John Van Voorst, London.
  5. 1868Church, A.H. (1868) Chemical researches on new and rare Cornish minerals. V. Cornwallite. The Journal of the Chemical Society of London: 21: 276-279.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cornwallite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cornwallite-1133},
  note      = {Accessed 2026-05-11}
}