Chibaite

SiO2 · n(CH4,C2H6,C3H8,C4H10) (nmax = 3/17)
IMA status
  • Approved
IMA symbol
Cib
IMA approved
2009
Also known as
  • Chibaiet
  • IMA2008-067

Where it forms, where it's found

Geological setting

In marine sediments of Early Miocene age.

Type locality
Arakawa
  1. Minamiboso city
  2. Chiba Prefecture
  3. Japan

35.1158°, 139.9385°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106.5 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Colorless
Streak
White
Cleavage
None Observed
Density
1.933 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.470
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.470

Crystallography

Crystal system
Isometric
Space group
F2/d -3
Cell parameters
a = 19.3742(4) Å
Z
4
Morphology

As equant crystals displaying (111) and (100).

Twinning

Spinel law.

Type-locality form

As equant crystals; epitaxially intergrown with DOH-type silicate clathrate.

Crystal structure

Synonyms

  • Chibaiet
  • IMA2008-067

In other languages

German
Chibait · IMA 2008-067
Italian
chibaite
Japanese
千葉石

Classification

Strunz
10th ed.

4.DA

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DAWith small cations: Silica familyGroup
  • 4.DAChibaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. IMA website - approvals March 2009
  2. 2008Momma, K., Nishikubo, K., Takada, M., Takahashi, N., Honma, C., Nagase, T., Kudoh, Y., Ikeda, T. (2008) A clathrate mineral from Arakawa, Chiba Prefecture, Japan.
  3. 2011Momma, Koichi; Ikeda, Takuji; Nishikubo, Katsumi; Takahashi, Naoki; Honma, Chibune; Takada, Masayuki; Furukawa, Yoshihiro; Nagase, Toshiro; Kudoh, Yasuhiro (2011) New silica clathrate minerals that are isostructural with natural gas hydrates. Nature Communications, 2 (1). 196 doi:10.1038/ncomms1196DOI: 10.1038/ncomms1196
  4. 2013Momma, K., Miyawaki, R., Kuribayashi, T., Nagase, T. (2013) Single crystal X-ray diffraction experiments of a silica clathrate mineral chibaite. Photon Factory Activity Report 2012 #30 (2013) B.
  5. 2016Likhacheva, Anna Yu., Goryainov, Sergey V., Seryotkin, Yuriy V., Litasov, Konstantin D., Momma, Koichi (2016) Raman spectroscopy of chibaite, natural MTN silica clathrate, at high pressure up to 8 GPa. Microporous and Mesoporous Materials, 224. 100-106 doi:10.1016/j.micromeso.2015.11.033DOI: 10.1016/j.micromeso.2015.11.033
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chibaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chibaite-39335},
  note      = {Accessed 2026-05-11}
}