Cristobalite

SiO2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Crs
Discovered
1887
Also known as
  • Alpha-Cristobalite
  • b-Cristobalit
  • b-Cristobalita
  • +11 more

Where it forms, where it's found

Geological setting

Individual crystals in vesicles and lithophysae. A common constituent of opal (opal-C and opal-CT) in sedimentary rocks and siliceous sinter.

Type locality
Cerro San Cristóbal
  1. Pachuca Municipality
  2. Hidalgo
  3. Mexico
504recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous (Glassy)
Transparency
Transparent · Translucent
Colour
Colorless · white · also blue grey · brown · grey · yellow

Often white due to numerous cracks

Streak
White
Tenacity
brittle
Cleavage

None

Density
2.32 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.484 – 1.487
Surface relief
Low
Principal indices
nω 1.487 · nε 1.484
Birefringence
0.003
Pleochroism
Non-pleochroic
Extinction
Parallel
Luminescence
Non-fluorescent
UV response
Fluoresces weak red in shortwave. Anomalous green fluorescence reported from a few localities.
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#167
Cell parameters
a = 4.9709(1) Å · c = 6.9278(2) Å
Z
4
Morphology

Pseudo octahedral crystals, commonly dendritic, spherulites.

Twinning

On (111) (paramorphs of cubic β-Cristobalite twins)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen215.99931.998
53.26%
14SiSiliconSilicon128.08528.085
46.74%
Total60.083100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Ca
  • Al
  • K
  • Na
  • Ti
  • Mn
  • Mg
  • P

Synonyms

  • Alpha-Cristobalite
  • b-Cristobalit
  • b-Cristobalita
  • Christobalite
  • Cristobalitchalcedon
  • Crystobalite
  • Low-Cristobalite
  • Lussatine
  • Lussatit
  • Lussatita
  • Tiefcristobalit
  • α-Cristobalit
  • α-Cristobalita
  • α-Cristobalite

In other languages

French
14464-46-1 · Cristobalite
German
Cristobalit
Spanish
cristobalita
Italian
Cristobalite
Portuguese
cristobalita · Cristobalite
Japanese
クリストバライト · クリストバル石 · 方珪石
Chinese
方石英 · 方矽石
Russian
Кристобалит
Arabic
كريستوباليت

Classification

Strunz
10th ed.

4.DA.15

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DAWith small cations: Silica familyGroup
  • 4.DA.15CristobaliteSpecies
Dana
8th ed.

75.01.01.01

  • 75Tectosilicates Si Tetrahedral FrameworksClass
  • 75.01Si Tetrahedral Frameworks - SiO2 with [4] coordinated SiType
  • 75.01.01— unnamed intermediate level —Group
  • 75.01.01.01CristobaliteSpecies
CIM

7.8.5

  • 7Oxides and HydroxidesClass
  • 7.8Oxides of SiGroup
  • 7.8.5CristobaliteSpecies

Group, growth & confusion

Often grow together
6 minerals
Commonly confused with
7 minerals

Literature, links & citation

Citations
  1. 1887vom Rath, G. (1887) Ueber Cristobalit vom Cerro S. Cristóbal bei Pachuca (Mexico). Neues Jahrbuch für Mineralogie, Geologie und Paläontologie: 1987: 198-199.
  2. 1925Wyckoff, R.W.G. (1925) The crystal structure of the high temperature form of cristobalite (SiO2). American Journal of Science: 9: 448-459.
  3. 1932Barth, T.F.W. (1932) The cristobalite structures: I. High cristobalite. American Journal of Science: 23: 350-356.
  4. 1932Barth, T.F.W. (1932) The cristobalite structures: II. Low cristobalite. American Journal of Science: 24: 97-110.
  5. 1935Nieuwenkamp, W. (1935) Die Kristallstruktur des Tief-Cristobalits SiO2. Zeitschrift für Kristallographie, 92 (1-6). 82-88 doi:10.1524/zkri.1935.92.1.82DOI: 10.1524/zkri.1935.92.1.82
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cristobalite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cristobalite-1155},
  note      = {Accessed 2026-05-11}
}