Comblainite

Ni4Co3+2(CO3)(OH)12 · 3H2O
IMA status
  • Approved
IMA symbol
Cob
Discovered
1980
Also known as
  • Comblainiet
  • IMA1978-009

Where it forms, where it's found

Geological setting

Secondary product of nickel and cobalt sulfides in the oxidized zone of a uranium deposit.

Type locality
Shinkolobwe Mine
  1. Shinkolobwe
  2. Kambove Territory
  3. Haut-Katanga
  4. DR Congo

-11.0486°, 26.5508°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Turquoise-blue · yellow-green under a microscope
Density
3.05 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.684 – 1.69
Surface relief
High
Principal indices
nω 1.690 · nε 1.684
Pleochroism
Non-pleochroic
Optical colour
Yellow-green
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 3.038 Å · c = 22.79 Å
Morphology

cryptocrystalline crusts

Type-locality form

Turquoise-blue cryptocrystalline crusts on altered uraninite.

Comment

Point Group: 3 2/m, 3m, 32, 3, or 3. Space Group: R3m, R3m, R32, R3, or R3. Z = [3/8]

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
42.93%
28NiNickelNickel458.693234.772
35.00%
27CoCobaltCobalt258.933117.866
17.57%
1HHydrogenHydrogen181.00818.144
2.71%
6CCarbonCarbon112.01112.011
1.79%
Total670.775100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Comblainiet
  • IMA1978-009

In other languages

German
Comblainit · IMA 1978-009
Italian
Comblainite
Chinese
羟碳钴镍石

Classification

Strunz
10th ed.

5.DA.50

  • 5CarbonatesClass
  • 5.DCarbonates with additional anions, with H2ODivision
  • 5.DAWith medium-sized cationsGroup
  • 5.DA.50ComblainiteSpecies
Dana
8th ed.

16b.06.03.03

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.06AmBn(XO3)pZqxH2O & with (m+n):p = 8:1Type
  • 16b.06.03Sjorgrenite-Hydrotalcite Group (Hydrotalcite Subgroup:Rhombohedral)Group
  • 16b.06.03.03ComblainiteSpecies
CIM

11.14.11

  • 11CarbonatesClass
  • 11.14Carbonates of Co and NiGroup
  • 11.14.11ComblainiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1980Piret, Paul, Deliens, Michel (1980) La comblainite, (Ni2+x,Co3+1-x)(OH)2(CO3)(1-x)/2•yH2O, nouveau minéral du groupe de la pyroaurite. Bulletin de Minéralogie, 103 (1) 113-117 doi:10.3406/bulmi.1980.7381DOI: 10.3406/bulmi.1980.7381
  2. 1980Fleischer, M., Cabri, L. J., Chao, G. Y., Pabst, A. (1980) New mineral names. American Mineralogist, 65 (9-10). 1065-1070
  3. 2005(2005) Comblainite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2012Mills, S. J.; Christy, A. G.; Génin, J.-M. R.; Kameda, T.; Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5). 1289-1336 doi:10.1180/minmag.2012.076.5.10DOI: 10.1180/minmag.2012.076.5.10
  5. 2014Barton, I. F., Yang, H., Barton, M. D. (2014) The mineralogy, geochemistry, and metallurgy of cobalt in the rhombohedral carbonates. The Canadian Mineralogist, 52 (4) 653-670 doi:10.3749/canmin.1400006DOI: 10.3749/canmin.1400006
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Comblainite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/comblainite-1116},
  note      = {Accessed 2026-05-11}
}