Zaccagnaite

Zn4Al2(OH)12(CO3) · 3H2O
IMA status
  • Approved
IMA symbol
Zac
IMA approved
1997
Also known as
  • IMA1997-019

Where it forms, where it's found

Geological setting

Cavities in calcite veins in marble.

Type locality
Calagio quarries (Calagio Quarry
  1. Olmo Quarry)
  2. Colonnata quarrying basin
  3. Carrara
  4. Massa-Carrara Province
  5. Tuscany
  6. Italy

44.0837°, 10.1467°

9recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Subvitreous
Transparency
Transparent
Colour
White to pale yellow
Streak
White
Cleavage
Perfect

Perfect on (0001)

Density
2.84 g/cm³

Optical

Optical type
Uniaxial (-)
Luminescence
(not reported)

Crystallography

Crystal system
Hexagonal
Type-locality form

Minute hexagonal crystals < 0.2 mm long and 0.02-0.03 mm thick. These are covered by a thin crust of fraipontite and resemble so-called “Brugola” screws (i.e., set-screws).

Comment

see polytypes

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
45.45%
30ZnZincZinc465.380261.520
41.27%
13AlAluminiumAluminium226.98253.964
8.52%
1HHydrogenHydrogen181.00818.144
2.86%
6CCarbonCarbon112.01112.011
1.90%
Total633.621100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-019

In other languages

German
IMA 1997-019 · Zaccagnait
Italian
Zaccagnaite
Chinese
羟碳铝锌石

Classification

Strunz
10th ed.

5.DA.45

  • 5CarbonatesClass
  • 5.DCarbonates with additional anions, with H2ODivision
  • 5.DAWith medium-sized cationsGroup
  • 5.DA.45ZaccagnaiteSpecies
Dana
8th ed.

16b.06.01.04

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.06AmBn(XO3)pZqxH2O & with (m+n):p = 8:1Type
  • 16b.06.01Sjorgrenite-Hydrotalcite Group (Sojogrenite Subgroup:Hexagonal)Group
  • 16b.06.01.04ZaccagnaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2001Merlino, Stefano, Orlandi, Paolo (2001) Carraraite and zaccagnaite, two new minerals from the Carrara marble quarries: their chemical compositions, physical properties, and structural features. American Mineralogist, 86 (10) 1293-1301 doi:10.2138/am-2001-1017 DOI: 10.2138/am-2001-1017
  2. 2012Mills, S. J.; Christy, A. G.; Génin, J.-M. R.; Kameda, T.; Colombo, F. (2012) Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76 (5). 1289-1336 doi:10.1180/minmag.2012.076.5.10DOI: 10.1180/minmag.2012.076.5.10
  3. 2021(2021) Zaccagnaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zaccagnaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zaccagnaite-10810},
  note      = {Accessed 2026-05-11}
}