Apjohnite

Mn2+Al2(SO4)4 · 22H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Apj
Discovered
1847
Also known as
  • Apjohniet
  • Apjohnitt
  • Manganalaun

Where it forms, where it's found

Geological setting

Efflorescences.

Type locality
Maputo Bay
  1. Maputo
  2. Maputo Province
  3. Mozambique

-26.1881°, 32.8112°

27recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · light pink · light yellow · light green
Streak
White
Density
1.78 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 15°
Refractive index
1.478 – 1.482
Surface relief
Low
Principal indices
nα 1.478 · nβ 1.482 · nγ 1.482
Dispersion
none
Extinction
Y = b; Z ∧ c = 30°.
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 6.19 Å · b = 24.34 Å · c = 21.26 Å
Cell angles
β = 100.28 °
Ratio a:b:c
1 : 3.932 : 3.435
Z
4
Morphology

Crystals acicular aggregated into masses and crusts; also asbestiform.

Type-locality form

Transparent threads or fibers, resembling satin-spar.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
68.35%
16SSulfurSulfur432.060128.240
14.42%
25MnManganeseManganese154.93854.938
6.18%
13AlAluminiumAluminium226.98253.964
6.07%
1HHydrogenHydrogen441.00844.352
4.98%
Total889.456100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Apjohniet
  • Apjohnitt
  • Manganalaun

In other languages

French
Apjohnite
German
Apjohnit
Italian
Apjohnite
Chinese
锰铝矾

Classification

Strunz
10th ed.

7.CB.85

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.85ApjohniteSpecies
Dana
8th ed.

29.07.03.03

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.07AB2(XO4)4·H2OType
  • 29.07.03Halotrichite Group (Monoclinic with 22 H2O)Group
  • 29.07.03.03ApjohniteSpecies
CIM

25.9.7

  • 25SulphatesClass
  • 25.9Sulphates of MnGroup
  • 25.9.7ApjohniteSpecies

Group, growth & confusion

Often grow together
5 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1838Apjohn, J. (1838) On a new variety of Alumn. Philosophical Magazine and Journal of Science: 12: 103. [as Manganese Alum]
  2. 1838Kane, R. (1838) Ueber der Wirkung von Arsenikwasserstoff auf schwefelsaures Kupferoxyd und über den vom Dr. Apjohn zerlegten Mangan-alaun. Annalen der Physik: 44: 471-472.
  3. 1847Glocker, Ernst Friedrich (1847) Generum et specierum mineralium, secundum ordines naturales digestorum synopsis, omnium, quotquot adhuc reperta sunt, mineralium nomina complectens [A synopsis of the genera and species of minerals, according to their natural orders, including the names of all the minerals that have yet been discovered.]. Eduardus Anton. 348 pp.
  4. 1870Ludwig, H. (1870) Ueber den haarförmigen Manganalaun und das manganhaltige Bittersalz vom Boschjemansflusse. Archiv der Pharmacie: 193(2): 97-100.
  5. 1884Brown, W.G. (1884) A new hydrous manganous aluminic sulphate from Sevier Co., Tenn. American Chemical Journal: 6: 97-119.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Apjohnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/apjohnite-281},
  note      = {Accessed 2026-05-11}
}