Domeykite

Cu3As
IMA status
  • Approved
  • Grandfathered
IMA symbol
Do
Discovered
1845
Also known as
  • Arsenical Copper
  • Arsenical copper pyrites
  • Arsenikkupfer
  • +5 more

Where it forms, where it's found

Geological setting

Hydrothermal veins

Type locality
Los Algodones Mine
  1. El Arrayan
  2. Vicuña
  3. Elqui Province
  4. Coquimbo
  5. Chile

-30.0341°, -70.9178°

71recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Tin-white · steel-grey

Tarnishes yellowish, then brownish, finally iridescent.

Fracture
Irregular/Uneven
Density
7.2 g/cm³

Optical

Tropism
Isotropic
Reflectance R%
(41.1) 400, (41.4) 420, (41.7) 440, (43.1) 460, (45.2) 480, (47.5) 500, (49.3) 520, (50.7) 540, (52.2) 560, (53.6) 580, (54.5) 600, (54.9) 620, (54.8) 640, (54.6) 660, (54.4) 680, (54.6) 700
Reflected-light panel
49.6 %isotropic · single curve
Specimen sRGB 255, 175, 85
White reference100 % reflector under same lamp

Crystallography

Crystal system
Isometric
Space group
#209
Cell parameters
a = 9.62 Å
Z
16
Morphology

Reniform, botyroidal, massive.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
71.79%
33AsArsenicArsenic174.92274.922
28.21%
Total265.560100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sb
  • S

Synonyms

  • Arsenical Copper
  • Arsenical copper pyrites
  • Arsenikkupfer
  • Arseniure de Cuivre
  • Cuivre Arsenical
  • Domeykiet
  • Domeykite-α
  • α-Domeykite

In other languages

French
Domeykite
German
Arsenikkupfer · Arsenkupfer · Domeykit
Spanish
Domeikita
Italian
Domeykite
Japanese
砒銅鉱
Chinese
砷铜矿
Arabic
دوميكيت

Classification

Strunz
10th ed.

2.AA.10b

  • 2Sulfides and SulfosaltsClass
  • 2.AAlloysDivision
  • 2.AAAlloys of metalloids with Cu, Ag, AuGroup
  • 2.AA.10bDomeykiteSpecies
Dana
8th ed.

02.02.02.01

  • 02SulfidesClass
  • 02.02AmBnXp, with (m+n):p = 3:1Type
  • 02.02.02Domeykite GroupGroup
  • 02.02.02.01DomeykiteSpecies
CIM

1.37

  • 1Elements and Alloys (including the arsenides, antimonides and bismuthides of Cu, Ag and Au)Class
  • 1.37— unnamed intermediate level —Group
  • 1.37DomeykiteSpecies

Group, growth & confusion

Often grow together
6 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1845Haidinger, W. (1845) Zweite Klasse: Geogenide. XIII. Ordnung. Kiese V. Kupperkies. Domeykit. in Handbuch der Bestimmenden Mineralogie, Bei Braumüller and Seidel (Wien): 559-562.
  2. 1904König, G. A.; Wright, F. Ε. (1904) Ueber die künstliche Darstellung von Krystallen des Mohawkits, des Domeykits, des Argentodomeykits, des Stibiodomeykits, des Keweenawits und anderer Arsenide. Zeitschrift für Krystallographie, 38 (1). 529-554 doi:10.1524/zkri.1904.38.1.529DOI: 10.1524/zkri.1904.38.1.529
  3. 1929Ramsdell, L. S. (1929) An X-ray study of the domeykite group. American Mineralogist, 14 (5) 188-196
  4. 1938Steenberg, B. (1938) The crystal structure of Cu3As and Cu3P. Arkiv Kemi Min. Geol. 12A, no. 26: 1: 15.
  5. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Domeykite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/domeykite-1306},
  note      = {Accessed 2026-05-11}
}