Emmerichite

Ba2Ti2Na3Fe3+(Si2O7)2O2F2
IMA status
  • Approved
IMA symbol
Emr
IMA approved
2013
Also known as
  • Emmerichiet
  • IMA2013-064

Where it forms, where it's found

Geological setting

Alkaline basalts. high-temperature pneumatolitic

Type locality
Rother Kopf
  1. Roth
  2. Gerolstein
  3. Gerolstein
  4. Vulkaneifel
  5. Rhineland-Palatinate
  6. Germany

50.2453°, 6.6214°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
brown
Streak
white
Tenacity
brittle
Cleavage
Perfect

on (100)

Density
3.864 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80° · 2V calc = 79°
Refractive index
1.725 – 1.759
Surface relief
High
Principal indices
nα 1.725 · nβ 1.728 · nγ 1.759
Pleochroism
Visible

moderate: Z (brown) ≥ Y (light brown) > X (greenish gray).

Dispersion
r > v, medium
UV response
Shows no fluorescence in the UV wavelength range
Michel-Lévy diagramhighlighted lineδ = 0.0340
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]340 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.960(1) Å · b = 7.098(1) Å · c = 5.4074(3) Å
Cell angles
γ = 96.368(1) °
Ratio a:b:c
1 : 0.356 : 0.271
Z
2
Type-locality form

Emmerichite forms lamellar (often plank-like) crystals up to 0.05 × 0.3 × 0.5 mm in size and clusters up to 1mm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium2137.327274.654
30.47%
8OOxygenOxygen1615.999255.984
28.39%
14SiSiliconSilicon428.085112.340
12.46%
22TiTitaniumTitanium247.86795.734
10.62%
11NaSodiumSodium322.99068.970
7.65%
26FeIronIron155.84555.845
6.19%
9FFluorineFluorine218.99837.996
4.22%
Total901.523100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Emmerichiet
  • IMA2013-064

In other languages

German
Emmerichit · IMA 2013-064
Italian
emmerichite

Classification

Strunz
10th ed.

9.BE.25

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.25EmmerichiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No.17. Mineralogical Magazine, 77 (7) 2997-3005 doi:10.1180/minmag.2013.077.7.09DOI: 10.1180/minmag.2013.077.7.09
  2. 2014Aksenov, Sergey M., Rastsvetaeva, Ramiza K., Chukanov, Nikita V. (2014) The crystal structure of emmerichite Ва2Na3Fe3+Ti2(Si2O7)2O2F2, a new lamprophyllite-group mineral. Zeitschrift für Kristallographie – Crystalline Materials, 229 (1). 1-7 doi:10.1515/zkri-2013-1698DOI: 10.1515/zkri-2013-1698
  3. 2014Chukanov, N.V., Rastsvetaeva, R.K., Aksenov, D.M., Blass, G., Pekov, I.V., Belakovskiy, D.I., Tschörtner, J., Schüller, W., Ternes, B. (2014) Emmerichite, Ва2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2, a new lamprophyllite-group mineral from the Eifel volcanic region, Germany. New Data on Minerals: 49: 5–13.
  4. 2016(2016) Emmerichite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Emmerichite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/emmerichite-43943},
  note      = {Accessed 2026-05-11}
}