Lileyite

Ba2Ti2Na2Fe2+Mg(Si2O7)2O2F2
IMA status
  • Approved
IMA symbol
Lly
IMA approved
2011
Also known as
  • IMA2011-021
  • Lileyiet
  • Unnamed (Mg-analogue of Schüllerite)

Where it forms, where it's found

Geological setting

In miarolitic cavities of alkaline basalt.

Type locality
Löhley
  1. Üdersdorf
  2. Daun
  3. Vulkaneifel
  4. Rhineland-Palatinate
  5. Germany

50.1592°, 6.8114°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

on (001)

Density
3.776 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 75° · 2V calc = 86°
Refractive index
1.718 – 1.755
Surface relief
High
Principal indices
nα 1.718 · nβ 1.735 · nγ 1.755
Pleochroism
Visible

X = colourless, Y = light brown, Z = greyish brown

Dispersion
r > v, medium
Michel-Lévy diagramhighlighted lineδ = 0.0370
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]370 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation370 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.905(1) Å · b = 7.098(1) Å · c = 5.405(1) Å
Cell angles
β = 96.349(5) °
Ratio a:b:c
1 : 0.357 : 0.272
Unit cell volume
758.93 ų
Z
2
Morphology

The main crystal form is (100).

Type-locality form

Platy crystals up to 0.1 x 0.3 x 0.5 mm in size and their clusters up to 1 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium2137.327274.654
30.42%
8OOxygenOxygen1615.999255.984
28.35%
14SiSiliconSilicon428.085112.340
12.44%
22TiTitaniumTitanium247.86795.734
10.61%
26FeIronIron155.84555.845
6.19%
11NaSodiumSodium222.99045.980
5.09%
9FFluorineFluorine218.99837.996
4.21%
12MgMagnesiumMagnesium124.30524.305
2.69%
Total902.838100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sr
  • K
  • Mn
  • Nb

Synonyms

  • IMA2011-021
  • Lileyiet
  • Unnamed (Mg-analogue of Schüllerite)

In other languages

German
IMA 2011-021 · Lileyit
Italian
lileyite

Classification

Strunz
10th ed.

9.BE.25

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.25LileyiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  2. 2012Chukanov, Nikita V., Pekov, Igor V., Rastsvetaeva, Ramiza K., Aksenov, Sergey M., Zadov, Aleksandr E., Van, Konstantin V., Blass, Günter, Schüller, Willi, Ternes, Bernd (2012) Lileyite, Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2, a new lamprophyllite-group mineral from the Eifel volcanic area, Germany. European Journal of Mineralogy, 24 (1) 181-188 doi:10.1127/0935-1221/2012/0024-2174 DOI: 10.1127/0935-1221/2012/0024-2174
  3. 2013(2013) Lileyite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lileyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lileyite-41955},
  note      = {Accessed 2026-05-11}
}