Hejtmanite

Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2
IMA status
  • Approved
IMA symbol
Hej
Discovered
1989
IMA approved
1989
Also known as
  • Heijtmanit
  • Heijtmanita
  • Heijtmanite
  • +5 more

Where it forms, where it's found

Geological setting

A system of young segregation veins of manganoan arfvedsonite cutting foliated alkali granite and syenite.

Type locality
Mbolwe Hill
  1. Mkushi River area
  2. Mkushi
  3. Mkushi District
  4. Central Province
  5. Zambia

-14.0831°, 29.8331°

13recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brownish to golden yellow
Streak
Yellow, brown
Tenacity
brittle
Cleavage
Perfect

On (100)

Fracture
Irregular/Uneven
Density
3.97 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 76 – 76.8° · 2V calc = 76°
Refractive index
1.814 – 1.867
Surface relief
Very high
Principal indices
nα 1.814 · nβ 1.846 · nγ 1.867
Pleochroism

X = light yellow-green; Y = dark golden yellow; Z = light yellow.

Dispersion
r > v
Extinction
X = b; Y ∧ c = 37.9°; Z ∧ a = 15.9°.
UV response
Not fluorescent.
Notes

Absorption: Y > Z = X.

Michel-Lévy diagramhighlighted lineδ = 0.0530
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]530 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation530 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 10.716(2) Å · b = 13.795(3) Å · c = 11.778(2) Å
Cell angles
α = 90.07(3) ° · β = 112.24(3) ° · γ = 90.03(3) °
Ratio a:b:c
1 : 1.287 : 1.099
Unit cell volume
1612 ų
Parting
Poor parting on {0kl}
Type-locality form

Prismatic or platy crystals up to 1 mm long enclosed in manganoan arfvedsonite.

Comment

Space group setting is C-1

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
27.95%
56BaBariumBarium2137.327274.654
26.65%
25MnManganeseManganese454.938219.752
21.32%
14SiSiliconSilicon428.085112.340
10.90%
22TiTitaniumTitanium247.86795.734
9.29%
9FFluorineFluorine218.99837.996
3.69%
1HHydrogenHydrogen21.0082.016
0.20%
Total1030.474100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Nb
  • K
  • (Al, Mg, Na, Cl, Sr, Zr)

Synonyms

  • Heijtmanit
  • Heijtmanita
  • Heijtmanite
  • Hejtmaniet
  • IMA1989-038
  • Inylchekit
  • Inylchekita
  • Inylchekite

In other languages

German
Hejtmanit · IMA 1989-038
Italian
Hejtmanite
Chinese
海特曼石

Classification

Strunz
10th ed.

9.BE.55

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.55HejtmaniteSpecies
Dana
8th ed.

56.02.6b.02

  • 56Sorosilicates Si2o7 Groups, with Additional O, Oh, F and H2oClass
  • 56.02Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordinationType
  • 56.02.6b— unnamed intermediate level —Group
  • 56.02.6b.02HejtmaniteSpecies
CIM

14.9.18

  • 14Silicates not Containing AluminumClass
  • 14.9Silicates of TiGroup
  • 14.9.18HejtmaniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1992Jambor, John L. (1992) New Mineral Names. American Mineralogist, 77 (11-12) 1305-1309
  2. 1992Vrána, Stanislav, Rieder, Milan, Gunter, Mickey E. (1992) Hejtmanite, a manganese-dominant analogue of bafertisite, a new mineral. European Journal of Mineralogy, 4 (1) 35-44 doi:10.1127/ejm/4/1/0035 DOI: 10.1127/ejm/4/1/0035
  3. 2001(2001) Hejtmanite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2010Sokolova, E. V. (2010) Predictive crystal-chemical relations in Ti-silicates based on the TS block. Geology of Ore Deposits, 52 (5) 410-427 doi:10.1134/s1075701510050065DOI: 10.1134/s1075701510050065
  5. 2016Sokolova, E., Cámara, F., Hawthorne, F. C., Pautov, L. A. (2016) From structure topology to chemical composition. XX. Titanium silicates: the crystal structure of hejtmanite, Ba2Mn4Ti2(Si2O7)2O2(OH)2F2, a Group-II TS-block mineral. Mineralogical Magazine, 80 (5) 841-853 doi:10.1180/minmag.2016.080.026DOI: 10.1180/minmag.2016.080.026
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hejtmanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hejtmanite-1849},
  note      = {Accessed 2026-05-11}
}