Perraultite

KBa3Ca2Na2Mn16Ti8(Si2O7)8O8(OH)4(F,O,OH)8
IMA status
  • Approved
IMA symbol
Prt
Discovered
1984
IMA approved
1984
Also known as
  • IMA1984-033
  • Lepleite (of Pekov)
  • Lepleyite
  • +2 more

Where it forms, where it's found

Geological setting

Pegmatite dikes in nepheline syenite

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Orange brown
Streak
Light brown
Tenacity
very brittle
Cleavage
Very Good

(001) very good

Fracture
Irregular/Uneven
Density
3.71 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 64 – 66° · 2V calc = 62°
Refractive index
1.785 – 1.82
Surface relief
Very high
Principal indices
nα 1.785 · nβ 1.81 · nγ 1.82
Pleochroism
Strong

Z = dark brown, X : Y = light yellow

Dispersion
extreme, r<<v
UV response
Not fluorescent
Notes

X = b, Y Λ a = 19° in the obtuse β angle

Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 10.741(6) Å · b = 13.841(8) Å · c = 11.079(6) Å
Cell angles
α = 108.174(6) ° · β = 99.186(6) ° · γ = 89.99(1) °
Ratio a:b:c
1 : 1.289 : 1.031
Unit cell volume
1542.7 ų
Z
4
Morphology

Prismatic and flattened on (010), with elongation along [100], bound by (001), (010), (100) and a {-h0l} form, possibly (101).

Twinning

Swallow-tail contact twins are common, with (001) as the twin plane and composition plane.

Type-locality form

Orange-brown prismatic crystals to 0.5 mm.

Comment

Non-standard space-group setting C-1. Data from Sokolova et al. (2021). Previously thought to be monoclinic and have space group C2/m.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen8415.9991343.916
35.40%
25MnManganeseManganese1654.938879.008
23.15%
14SiSiliconSilicon1628.085449.360
11.84%
56BaBariumBarium3137.327411.981
10.85%
22TiTitaniumTitanium847.867382.936
10.09%
9FFluorineFluorine818.998151.984
4.00%
20CaCalciumCalcium240.07880.156
2.11%
11NaSodiumSodium222.99045.980
1.21%
19KPotassiumPotassium139.09839.098
1.03%
1HHydrogenHydrogen121.00812.096
0.32%
Total3796.515100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zr
  • Al
  • Fe
  • Mg

Synonyms

  • IMA1984-033
  • Lepleite (of Pekov)
  • Lepleyite
  • Perraultiet
  • Surkhobite

In other languages

German
IMA 1984-033 · Perraultit
Italian
Perraultite

Classification

Strunz
10th ed.

9.BE.67

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.67PerraultiteSpecies
Dana
8th ed.

78.01.05.02

  • 78Unclassified SilicatesClass
  • 78.01MiscellaneousType
  • 78.01.05Jinshianghite groupGroup
  • 78.01.05.02PerraultiteSpecies
CIM

17.8.3

  • 17Silicates Containing other AnionsClass
  • 17.8Silicates with niobate or tantalateGroup
  • 17.8.3PerraultiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1991Chao, George Y. (1991) Perraultite, a new hydrous sodium-potassium-barium-manganese-titanium-niobium silicate species from Mont Saint-Hilaire, Quebec. The Canadian Mineralogist, 29 (2) 355-358
  2. 1998Yamnova, N.A., Egorov-Tismenko, Yu.K., and Pekov, I.V. (1998) Crystal structure of perraultite from the Coastal Region of the Sea of Azov. Crystallography Reports: 41: 401-410.
  3. 1999Pekov, I.V., Belovitskaya, Yu.V., Kartashov, P.M., Chukanov, N.V., Yamnova, N.A., and Egorov-Tismenko, Yu.K. (1999) New data on perraultite (from the Azov Region) Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 127(1): 112-120 (in Russian).
  4. 2001Jambor, J.L. and Roberts, A.C. (2001) New mineral names. American Mineralogist: 86: 197-200.
  5. 2001(2001) Perraultite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Perraultite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/perraultite-3167},
  note      = {Accessed 2026-05-11}
}