Hibonite

CaAl12O19
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hbn
Discovered
1953

Where it forms, where it's found

Geological setting

Found in an alluvial deposit close to thorianite-bearing skarns

In metamorphosed limestone, pyroxenite, gneiss, and granulite of the amphibolite to granulite facies; alluvials

Type locality
Esiva eluvials
  1. Esiva
  2. Maromby
  3. Amboasary Sud District
  4. Anosy
  5. Madagascar
76recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789107.5 – 8/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Black to brownisk black · purple

Reddish-brown and translucent in thin fragments

Streak
Brown
Cleavage
Perfect

on (0001)

Fracture
Sub-Conchoidal
Density
3.83 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.79 – 1.807
Surface relief
High
Principal indices
nω 1.807 · nε 1.79 · n 1.807
Pleochroism
Visible

O brownish-gray, E gray.

Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/mmc
Cell parameters
a = 5.613(1) Å · c = 22.285(8) Å
Z
2
Morphology

Hexagonal prismatic crystals, flattened on (0001), also showing steep pyramids. The face (0001) is commonly divided into 6 sectors.

Parting
on (1010)
Type-locality form

Small up to 4 cm large, black hexagonal prismatic crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
13AlAluminiumAluminium1226.982323.784
48.48%
8OOxygenOxygen1915.999303.981
45.52%
20CaCalciumCalcium140.07840.078
6.00%
Total667.843100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Si

In other languages

German
Hibonit
Spanish
Hibonita
Italian
Hibonite
Chinese
黑铝钙石

Classification

Strunz
10th ed.

4.CC.45

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CCWith large and medium-sized cationsGroup
  • 4.CC.45HiboniteSpecies
Dana
8th ed.

07.04.01.01

  • 07Multiple OxidesClass
  • 07.04AB12X19Type
  • 07.04.01(Hexagonal, P63/mmc)Group
  • 07.04.01.01HiboniteSpecies
CIM

7.9.11

  • 7Oxides and HydroxidesClass
  • 7.9Oxides of TiGroup
  • 7.9.11HiboniteSpecies

Group, growth & confusion

In the same group
1 members
Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1955Delbos, L. (1955) Note sur le gisement d'un mineral nouveau "la hibonite" de' l'Androy Mandrareen. Rapport Annuel du Service Geologique pour 1955, Tananarivo: 143-144.
  2. 1956Curien H, Guillemin C, Orcel J, Sternberg M (1956) La hibonite, nouvelle espèce minérale. Comptes Rendus Hebdomadaires des Séances de l’Académie des Sciences 242, 2845-2847
  3. 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (1-2). 117-124
  4. 1960Behier, Jean (1960) Contribution à la minéralogie de Madagascar. Annales géologiques de Madagascar Vol. 29. République Malgache
  5. 1988Beckett, John R, Live, David, Tsay, Fun-Dow, Grossman, Lawrence, Stolper, Edward (1988) Ti3+ in meteoritic and synthetic hibonite. Geochimica et Cosmochimica Acta, 52 (6) 1479-1495 doi:10.1016/0016-7037(88)90219-0DOI: 10.1016/0016-7037(88)90219-0
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hibonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hibonite-1897},
  note      = {Accessed 2026-05-11}
}