Corundum

Al2O3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Crn
Also known as
  • a-Corundum
  • Adamas siderites
  • Ajatit
  • +34 more

History

Long before anyone had a single word for it, corundum hid behind a scattering of old gem names. Writers called the red and blue stones adamant, sapphire, ruby, hyacinthos and asteria — all, we now know, the same mineral wearing different colours. In China, four polished corundum axes from the Liangzhu and Sanxingcun cultures, dated to about 2500 BC, show the stone was being worked into tools that early.

The modern name arrived in the early 18th century. In 1725 the English naturalist John Woodward wrote it as corinvindum, borrowing from the Sanskrit kuruvinda — a word for ruby. The root runs deeper still, into the Tamil-Dravidian kurundam, meaning ruby-sapphire. The spelling settled into its present form in 1794, when the Irish chemist Richard Kirwan first used corundum.

Making it in the laboratory

The 19th century turned corundum from a found stone into a made one. In 1837 the French chemist Marc Antoine Gaudin produced the first synthetic rubies, heating alumina — aluminium oxide — with a trace of chromium for colour. A decade later, in 1847, J. J. Ebelmen grew white synthetic sapphires by reacting alumina in boric acid.

The breakthrough came from Auguste Verneuil. The French chemist had worked on melting rubies since the 1880s. He sealed his notes with the Paris Academy of Science, then announced the method in 1902. His flame-fusion process drips powdered alumina through an oxyhydrogen flame, letting the molten droplets build up into a single crystal called a boule. By 1903 he could make rubies on a commercial scale. It was the first practical way to grow large flawless gems, and it remains the cheapest.

Industrial & practical applications

At a hardness of 9 on the ten-point Mohs scale — the scratch test that ranks minerals by which can scratch which — corundum is beaten only by diamond. That hardness is the source of nearly everything people do with it. Its main job is to grind, polish and cut other materials.

The grinding grade is emery, a black granular corundum naturally mixed with iron oxides such as magnetite and hematite. Emery coats sandpaper and the large tools that machine metals, plastics and wood. Most abrasive corundum today is not dug from the ground at all but manufactured from bauxite, the aluminium ore. Natural corundum for abrasives is still mined in Zimbabwe, Pakistan, Afghanistan, Russia, Sri Lanka and India, with emery-grade stone coming from the Greek island of Naxos.

The flame-fusion process makes corundum to order, and that synthetic stock does more than grinding. It is machined into mechanical parts — tubes, rods and bearings. The same hardness gives scratch-resistant optics and the clear covers on watch faces. Because synthetic sapphire stays transparent from ultraviolet through to infrared light, it serves as instrument windows on satellites and spacecraft. Its toughness has also drawn it into ceramic armour.

Corundum is also a laser crystal. A rod of synthetic ruby — corundum coloured red by chromium — is the gain medium in the ruby laser, the part that actually amplifies the light. Ruby lasers have given ground to better materials, but they still serve where short pulses of red light are needed. Its red and blue gem varieties, ruby and sapphire, remain the best-known faces of the species, prized as cut stones.

Where it forms, where it's found

Geological setting

Silica-poor rocks, such as Nepheline-Syenites, alkali igneous undersaturated rocks, contact aureoles in altered aluminous shales, aluminous xenoliths in high temperature plutonic and hypabyssal rocks, metamorphosed bauxite deposits, and as a detrital material in sediments.

1,601recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789109/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Colourless · blue · red · pink · yellow · grey · golden-brown
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Conchoidal
Density
3.98 g/cm³

Optical

Optical type
Uniaxial (-) · 2V measured = 58°
Refractive index
1.759 – 1.772
Surface relief
High
Principal indices
nω 1.767 – 1.772 · nε 1.759 – 1.763
Birefringence
Low, first-order greys and whites.
Pleochroism
Not Visible

Weak in sapphire (e = blue-green to yellow-green, o = pale to deep blue), otherwise none visible.

Optical colour
Colourless
Notes

Asterism often present due to oriented needle-like inclusions or to colloidal or other material deposited in oriented tubules.

Michel-Lévy diagramhighlighted lineδ = 0.0085
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]85 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation85 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#98
Cell parameters
a = 4.75 Å · c = 12.982 Å
Unit cell volume
253.54 ų
Z
6
Morphology

Often steep pyramidal on w, z, E, or ω. Barrel-shaped crystals that are often rough and rounded, of considerable size at times, varying from short prismatic [0001] with a large base to steep pyramidal. Less commonly, flat tabular (0001) or rhombohedral. Striae on (0001) parallel [01_10]. Lines in the direction [11_20] divide the base into six sectors at times. Forms include (0001), (1000), (1120), (7180), (1015), (1013), (1012), (1011), (7072), (7071), (0111), (0221), (0772), (2245), (2243), {7·7·_14·9}, (1121), {7·7·_14·6}, (4488), {11·11·_22·6}, (2241), {7·7·_14·3}, {8·8·_16·3}, (4481), {14·14·_28·3}, (4265), (3254), {2·8·_10·9}

Twinning

1. Common (1011); usually lamellar, producing a lamellar structure and striae on c and r. Less commonly penetration twins or arrowhead twins with crystals tabular (1120). 2. On (0001), less common. Pressure twinning produced on (1011), and on (0001).

Parting
Rhombohedral and basal parting (0001), sometimes perfect but interrupted; also on (1011) due to exsolution (Boehmite), observed on large blocks (Georgia, USA).
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
13AlAluminiumAluminium226.98253.964
52.93%
8OOxygenOxygen315.99947.997
47.07%
Total101.961100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cr
  • Fe
  • V
  • Ti

Synonyms

  • a-Corundum
  • Adamas siderites
  • Ajatit
  • Alumina
  • Ayatit
  • Ayatita
  • Ayatite
  • Corindon adamantin
  • Corindon harmophane
  • Corinendum
  • Corinindum
  • Corivendum
  • Corivindum
  • Corrindon
  • Corundit
  • Corundita
  • Corundum-alpha
  • Corundum-α
  • Corundumit
  • Corundumita
  • Corundumite
  • Demantspath
  • Harmophane
  • Karund
  • Korunduvit
  • Korunduvita
  • Korunduvite
  • Soimontit
  • Soimontita
  • Soimontite
  • Spath Adamantin
  • White Sapphire
  • Zircolita
  • Zircolite
  • Zircolith
  • α-Alumina
  • α-Corundum

In other languages

French
1302-74-5 · Alumine alpha · Ayatite · corindon · Corindon adamantin · Corindon harmophane · Corundite · Corundumite · Spath adamantin · Télésie · Zircolite
German
Adamantin · Edelkorund · Korund
Spanish
corindón · corundo · óxido de aluminio
Italian
corindone
Portuguese
Corindo · coríndon
Japanese
コランダム · 鋼玉
Chinese
刚玉 · 剛玉 · 金剛砂 · 鋼玉
Simplified Chinese
刚玉
Traditional Chinese
剛玉
Russian
корунд
Arabic
قرند · كورندم · كوروند
Hindi
कुरुविन्द

Classification

Strunz
10th ed.

4.CB.05

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.05CorundumSpecies
Dana
8th ed.

04.03.01.01

  • 04Simple OxidesClass
  • 04.03A2X3Type
  • 04.03.01Corundum-Hematite group (Rhombohedral: R-3c)Group
  • 04.03.01.01CorundumSpecies
CIM

7.6.1

  • 7Oxides and HydroxidesClass
  • 7.6Oxides of AlGroup
  • 7.6.1CorundumSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Pignatelli, I., Nespolo, M., Pardieu, V., Giuliani, G., Morlot, C. (2024): Basal twinning of Greenland. Mineralogy and Petrology, 118, (in press).
  2. 1565Gesner, C. (1565) Gemmis, quae erant in veste Aaronis, Liber Graecus, & e regione Latinus, Iola Hierotarantino interprete: cum Corollario Conradi Gesneri. in Sancti Patris Epiphanii Episcopi Cypri ad Diodorum Tyri episcopum, De XII, 1-29.
  3. 1805Haüy (1805): Ann. Phys.: 20: 187.
  4. 1806Lucas (1806): 1: 257.
  5. 1891Edmond Frémy (1891): Synthèse du rubis. Vve. Ch. Dunod, France. [https://archive.org/details/SyntheseDuRubis]
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Corundum — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/corundum-1136},
  note      = {Accessed 2026-05-11}
}