Huemulite

Na4MgV5+10O28 · 24H2O
IMA status
  • Approved
IMA symbol
Hml
Discovered
1959
Also known as
  • Huemuliet
  • IMA1965-012

Where it forms, where it's found

Geological setting

A post-mining mineral derived from Cu-U sandstone/conglomerate deposits.

Type locality
Huemul Mine
  1. Pampa Amarilla mining district
  2. Malargüe Department
  3. Mendoza Province
  4. Argentina

-35.7694°, -69.6583°

20recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellowish orange to orange
Streak
Yellow
Tenacity
brittle
Cleavage
Perfect

(001) perfect; (010) good

Density
2.39 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 20 – 25° · 2V calc = 40°
Refractive index
1.679 – 1.742
Surface relief
High
Principal indices
nα 1.679 · nβ 1.734 · nγ 1.742
Birefringence
0.063
Pleochroism
Visible

X= light yellow Y= golden yellow Z= yellowish orange

Dispersion
r > v strong
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0630
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]630 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation630 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 11.770 Å · b = 11.838 Å · c = 9.018(9) Å
Cell angles
α = 107.2 ° · β = 112.2 ° · γ = 101.5 °
Ratio a:b:c
1 : 1.006 : 0.766
Z
1
Morphology

Synthetic crystals are pseudohexagonal elongated along [100].

Type-locality form

Fibrous crusts and films, also fine-grained granular.

Comment

Point Group: _1 or 1; Space Group: P_1 or P1.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5215.999831.948
55.24%
23VVanadiumVanadium1050.942509.420
33.83%
11NaSodiumSodium422.99091.960
6.11%
1HHydrogenHydrogen481.00848.384
3.21%
12MgMagnesiumMagnesium124.30524.305
1.61%
Total1506.017100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Huemuliet
  • IMA1965-012

In other languages

French
Huemulite
German
Huemulit · IMA1965-012
Spanish
huemulita
Italian
Huemulite

Classification

Strunz
10th ed.

4.HG.10

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HGUnclassified V oxidesGroup
  • 4.HG.10HuemuliteSpecies
Dana
8th ed.

47.02.03.01

  • 47Vanadium OxysaltsClass
  • 47.02Anhydrous Vanadium Oxysalts Containing Hydroxyl or HalogenType
  • 47.02.03— unnamed intermediate level —Group
  • 47.02.03.01HuemuliteSpecies
CIM

21.1.6

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.6HuemuliteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1966Gordillo, C. E., Linares, E., Toubes, R. O., Winchell, H. (1966) Huemulite, Na4MgV10O28·24H2O, a new hydrous sodium and magnesium vanadate from Huemul Mine, Mendoza Province, Argentina. American Mineralogist, 51 (1-2) 1-13
  2. 1969Fleischer, Michael (1969) New Mineral Names. American Mineralogist, 54 (1-2) 326-330
  3. 2004Frost, Ray L, Erickson, Kristy L, Weier, Matt L (2004) Hydrogen bonding in selected vanadates: a Raman and infrared spectroscopy study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60 (10) 2419-2423 doi:10.1016/j.saa.2003.12.017DOI: 10.1016/j.saa.2003.12.017
  4. 2005(2005) Huemulite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2011Colombo, F., Baggio, R., Kampf, A. R. (2011) The crystal structure of the elusive huemulite. The Canadian Mineralogist, 49 (3). 849-864 doi:10.3749/canmin.49.3.849DOI: 10.3749/canmin.49.3.849
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Huemulite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/huemulite-1941},
  note      = {Accessed 2026-05-11}
}