Kryzhanovskite

(Fe3+,Mn2+)3(PO4)2(OH,H2O)3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kry
Discovered
1950
Also known as
  • Kruzhanovskit
  • Kruzhanovskita
  • Kruzhanovskite
  • +8 more

Where it forms, where it's found

Geological setting

Low-temperature oxidation product of phosphate minerals.

Type locality
Ak-Kezen' pegmatite
  1. Belogorskiy
  2. Ulan District
  3. East Kazakhstan Region
  4. Kazakhstan
32recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Deep red-brown · dark blackish brown to light golden-brown

Bronze on cleavage surfaces.

Streak
Yellowish brown
Cleavage
Perfect

(001)

Fracture
Irregular/Uneven
Density
3.31 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40 – 82°
Refractive index
1.79 – 1.82
Surface relief
Very high
Principal indices
nα 1.79 · nβ 1.80 · nγ 1.82
Pleochroism
Strong

X = wine-yellow; Y = orange-brown; Z = reddish brown.

Dispersion
r < v or r > v, strong.
Notes

Optic axial plane (OAP) ⊥ (001).

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 9.450(2) Å · b = 10.013(2) Å · c = 8.179(2) Å
Ratio a:b:c
1 : 1.060 : 0.866
Z
4
Type-locality form

Poorly formed crystals of prismatic habit, up to 2-3 cm in diameter.

Comment

Space Group: P bna

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
35.70%
26FeIronIron355.845167.535
26.71%
25MnManganeseManganese354.938164.814
26.27%
15PPhosphorusPhosphorus230.97461.948
9.87%
1HHydrogenHydrogen91.0089.072
1.45%
Total627.355100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kruzhanovskit
  • Kruzhanovskita
  • Kruzhanovskite
  • Kruzhanowskit
  • Kryjanovskit
  • Kryjanovskita
  • Kryjanovskite
  • Kryschanowskit
  • Kryshanovskit
  • Kryshanowskit
  • Kryzhanovskiet

In other languages

German
Kryzhanovskit
Italian
Kryzhanovskite

Classification

Strunz
10th ed.

8.CC.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CCWith only medium-sized cations, RO4:H2O = 1:1.5Group
  • 8.CC.05KryzhanovskiteSpecies
Dana
8th ed.

40.03.02.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.02Phosphoferrite GroupGroup
  • 40.03.02.02KryzhanovskiteSpecies
CIM

19.12.17

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.17KryzhanovskiteSpecies

Group, growth & confusion

In the same group
5 members

Literature, links & citation

Citations
  1. 1950Ginzburg, A.I. (1950) Kryzhanovskite, a new phosphate mineral. Doklady Akademii Nauk SSSR: 72: 763-766.
  2. 1951Fleischer, M. (1951) New mineral names. American Mineralogist, 36 (3-4). 381-384
  3. 1971Moore, Paul Brian (1971) The Fe2+3(H2O)n(PO4)2 homologous series: Crystal-chemical relationships and oxidized equivalents. American Mineralogist, 56 (1-2) 1-17
  4. 1974MOORE, PAUL BRIAN (1974) Evidence for a complete mixed valence solid solution series in Fe23+(H2O)3[PO4]2 (phosphoferrite) Fe33+(OH)3[PO4]2 (kryzhanovskite). Nature, 251 (5473). 305-306 doi:10.1038/251305a0DOI: 10.1038/251305a0
  5. 1976Moore, Paul Brian., Araki, Takaharu. (1976) Mixed-valence solid-solution series. Crystal structures of phosphoferrite, Fe32+(H2O)3[PO4]2, and kryzhanovskite, Fe33+(OH)3[PO4]2. Inorganic Chemistry, 15 (2) 316-321 doi:10.1021/ic50156a015DOI: 10.1021/ic50156a015
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kryzhanovskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kryzhanovskite-2281},
  note      = {Accessed 2026-05-11}
}