Phosphoferrite

Fe2+3(PO4)2 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Phf
Discovered
1920
Also known as
  • Iron-Reddingite
  • Phosphoferriet
  • Reddingite (of Steinmetz)

Where it forms, where it's found

Geological setting

Pegmatite

Type locality
Hühnerkobel Mine (Hennenkobel Mine)
  1. Rabenstein
  2. Zwiesel
  3. Regen District
  4. Lower Bavaria
  5. Bavaria
  6. Germany

49.0517°, 13.1697°

28recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · pale green · reddish brown (altered) · colourless to faintly tinted green in transmitted light.
Tenacity
brittle
Cleavage
Poor/Indistinct

On (010), poor.

Fracture
Irregular/Uneven
Density
3 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 68° · 2V calc = 66°
Refractive index
1.663 – 1.7
Surface relief
High
Principal indices
nα 1.663 – 1.672 · nβ 1.674 – 1.680 · nγ 1.699 – 1.700
Dispersion
r > v strong
Extinction
Parallel. X = a; Y = b; Z = c.
Michel-Lévy diagramhighlighted lineδ = 0.0320
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]320 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation320 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#70
Cell parameters
a = 9.41 Å · b = 10.02 Å · c = 8.66 Å
Ratio a:b:c
1 : 1.065 : 0.920
Morphology

Crystals octahedral with large (111), or tabular (010). The crystals frequently grow in parallel groupings. Massive, granular; coarsely fibrous.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
42.77%
26FeIronIron355.845167.535
40.71%
15PPhosphorusPhosphorus230.97461.948
15.05%
1HHydrogenHydrogen61.0086.048
1.47%
Total411.520100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Iron-Reddingite
  • Phosphoferriet
  • Reddingite (of Steinmetz)

In other languages

German
Phosphoferrit
Italian
Fosfoferrite · Phosphoferrite

Classification

Strunz
10th ed.

8.CC.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CCWith only medium-sized cations, RO4:H2O = 1:1.5Group
  • 8.CC.05PhosphoferriteSpecies
Dana
8th ed.

40.03.02.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.02Phosphoferrite GroupGroup
  • 40.03.02.01PhosphoferriteSpecies
CIM

19.12.19

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.19PhosphoferriteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1915Laubmann, H.; Steinmetz, H. (1915) Phosphatführende Pegmatite des Oberpfälzer und Bayerischen Waldes. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 55 (1-6). 523-586 doi:10.1524/zkri.1915.55.1.523DOI: 10.1524/zkri.1915.55.1.523
  2. 1921Wherry, E.T., Gordon, S.G., Foshag, W.F. (1921) New minerals. American Mineralogist: 6: 63-68.
  3. 1926Steinmetz, H. (1926) Phosphophyllit und Reddingit von Hagendorf. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 64 (1-6). 405-412 doi:10.1524/zkri.1926.64.1.405DOI: 10.1524/zkri.1926.64.1.405
  4. 1928Foshag, W.F. (1928) New mineral names. American Mineralogist: 13: 32-34.
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphoferrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphoferrite-3199},
  note      = {Accessed 2026-05-11}
}