Lacroixite

NaAl(PO4)F
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lac
Discovered
1914
Also known as
  • Lacroixiet

Where it forms, where it's found

Geological setting

Granite pegmatites

Type locality
Greifensteine
  1. Ehrenfriedersdorf
  2. Erzgebirgskreis
  3. Saxony
  4. Germany

50.6486°, 12.9311°

25recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · resinous
Transparency
Translucent
Colour
Colourless · light yellow · light green · almost white · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

Parallel to (111) and 1_11) only.

Fracture
Irregular/Uneven
Density
3.126 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 89° · 2V calc = 88°
Refractive index
1.546 – 1.58
Surface relief
Moderate
Principal indices
nα 1.546 · nβ 1.563 · nγ 1.580
Birefringence
0.034
Dispersion
Slight r<v
Extinction
Inclined
Michel-Lévy diagramhighlighted lineδ = 0.0340
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]340 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation340 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 6.414 Å · b = 8.207 Å · c = 6.885 Å
Cell angles
β = 115.47 °
Ratio a:b:c
1 : 1.280 : 1.073
Morphology

Usually massive or intergrown with other minerals. Rarely observed as fragmentary crystals.

Type-locality form

intergrowths, alteration rims, druses

Comment

Pseudo-orthorhombic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
39.04%
15PPhosphorusPhosphorus130.97430.974
18.89%
13AlAluminiumAluminium126.98226.982
16.46%
11NaSodiumSodium122.99022.990
14.02%
9FFluorineFluorine118.99818.998
11.59%
Total163.940100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Lacroixiet

In other languages

French
Lacroixite
German
Lacroixit
Spanish
Lacroixita
Italian
Lacroixite

Classification

Strunz
10th ed.

8.BH.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.10LacroixiteSpecies
Dana
8th ed.

41.05.05.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.05Lacroixite GroupGroup
  • 41.05.05.01LacroixiteSpecies
CIM

22.1.2

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.1Phosphates, arsenates or vanadates with fluorideGroup
  • 22.1.2LacroixiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1914Slavik, M.F. (1914) Sur les fluorophosphates ternaires de Al2O3, RO et R2O (morinite, ježekite, lacroixite). Bulletin de la Société Française de Minéralogie et de Cristallographie: 37: 152-162.
  2. 1914Slavík (1914) Ac. sc. Bohéme Bulletin, no. 4: 19.
  3. 1915Slavík (1915) Ac. sc. Bohéme: 20: 372.
  4. 1934Larsen, E.S.; Berman, H. (1934) The microscopic determination of the nonopaque minerals. Bulletin of the US Geological Survey Vol. 848. US Geological Survey p.1-266. doi:10.3133/b848 DOI: 10.3133/b848
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Lacroixite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/lacroixite-2310},
  note      = {Accessed 2026-05-11}
}