Mansfieldite

Al(AsO4) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mfd
Discovered
1948
Also known as
  • Mansfieldiet

Where it forms, where it's found

Type locality
Hobart Butte
  1. Black Butte Mining District
  2. Lane County
  3. Oregon
  4. USA

43.6085°, -123.1076°

48recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
White · light gray · colourless in transmitted light.
Cleavage
Imperfect/Fair

On (201), imperfect; on (001) and (100) in traces.

Fracture
Sub-Conchoidal
Density
3.03 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30 – 68° · 2V calc = 38 – 82°
Refractive index
1.622 – 1.663
Surface relief
Moderate
Principal indices
nα 1.622 – 1.631 · nβ 1.624 – 1.649 · nγ 1.642 – 1.663
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]260 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation260 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#61
Cell parameters
a = 8.8218 Å · b = 9.8252 Å · c = 10.1163 Å
Ratio a:b:c
1 : 1.114 : 1.147
Unit cell volume
876.8 ų
Morphology

Porous, cellular masses and crusts of spherulitic fibers.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
47.54%
33AsArsenicArsenic174.92274.922
37.10%
13AlAluminiumAluminium126.98226.982
13.36%
1HHydrogenHydrogen41.0084.032
2.00%
Total201.930100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Mansfieldiet

In other languages

French
Mansfieldite
German
Mansfieldit
Italian
Mansfieldite

Classification

Strunz
10th ed.

8.CD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CDWith only medium-sized cations, RO4:H2O = 1:2Group
  • 8.CD.10MansfielditeSpecies
Dana
8th ed.

40.04.01.04

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.04(AB)5(XO4)2·xH2OType
  • 40.04.01Variscite GroupGroup
  • 40.04.01.04MansfielditeSpecies
CIM

20.4.1

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.4Arsenates of Group III metals (Al, rare earths)Group
  • 20.4.1MansfielditeSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1948Allen, Victor T., Fahey, Joseph J. (1948) Mansfieldite, a new arsenate, the aluminum analogue of scorodite, and the mansfieldite-scorodite series. American Mineralogist, 33 (3-4) 122-134
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1963Walenta, K. (1963) Mansfieldit von Neubulach im württembergischen Schwarzwald. Neues Jahrbuch für Mineralogie - Monatshefte, 1963. 79-87
  4. 2000Harrison, William T. A. (2000) Synthetic mansfieldite, AlAsO4·2H2O. Acta Crystallographica Section C Crystal Structure Communications, 56 (10). e421 doi:10.1107/s0108270100011690DOI: 10.1107/s0108270100011690
  5. 2005(2005) Mansfieldite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mansfieldite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mansfieldite-2568},
  note      = {Accessed 2026-05-11}
}