Zeunerite

Cu(UO2)2(AsO4)2 · 12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Zeu
Discovered
1872
Also known as
  • Kupferarsenuranit
  • Zeuneriet
  • Zeunerite (of Frondel)

Where it forms, where it's found

Geological setting

Secondary mineral in oxidation zone of arsenic bearing hydrothermal uranium deposits.

Type locality
Walpurgis Flacher vein
  1. Weißer Hirsch Mine (shaft 3)
  2. Neustädtel
  3. Schneeberg
  4. Erzgebirgskreis
  5. Saxony
  6. Germany

50.5883°, 12.6389°

199recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow-green · emerald-green
Tenacity
brittle
Cleavage
Perfect

Perfect on (001); distinct on (100)

Fracture
Micaceous
Density
3.47 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.582 – 1.613
Surface relief
Moderate
Principal indices
nω 1.610 – 1.613 · nε 1.582 – 1.585
Birefringence
0.028
Pleochroism
Visible

O = Blue-green E = Pale blue-green

Extinction
Parallel
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0280
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]280 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation280 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#176
Cell parameters
a = 7.1797(3) Å · c = 20.857(1) Å
Unit cell volume
1075.1 ų
Z
2
Morphology

Crystals flat tabular on (001). Subparallel growths common.

Comment

Data for synthetic crystal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium2238.029476.058
43.37%
8OOxygenOxygen2415.999383.976
34.98%
33AsArsenicArsenic274.922149.844
13.65%
29CuCopperCopper163.54663.546
5.79%
1HHydrogenHydrogen241.00824.192
2.21%
Total1097.616100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kupferarsenuranit
  • Zeuneriet
  • Zeunerite (of Frondel)

In other languages

French
Zeunérite
German
Zeunerit
Spanish
Zeunerita
Italian
zeunerite
Chinese
铜砷铀云母

Classification

Strunz
10th ed.

8.EB.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EBUO2:RO4 = 1:1Group
  • 8.EB.05ZeuneriteSpecies
Dana
8th ed.

40.2a.14.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.2aAB2(XO4)2·xH2O, containing (UO2)2+Type
  • 40.2a.14— unnamed intermediate level —Group
  • 40.2a.14.01ZeuneriteSpecies
CIM

20.7.5

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.7Arsenates of UGroup
  • 20.7.5ZeuneriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1872Weisbach, A. (1872) Mittheilungen an Professor H.B. Geinitz, Freiberg, den 9. Februar 1872. Neues Jahrbuch für Mineralogie, Geologie und Palaontologie: 1872: 206-208.
  2. 1873Weisbach, A. (1873) Neue Uranerze von Neustädtel bei Schneeberg (Freiberger Jarbuch). Neues Jahrbuch für Mineralogie, Geologie und Palaontologie: 1873: 314-317.
  3. 1877Weisbach, A. (1877) Mineralogische Mittheilungen. Jahrbuch für das Berg- und Hüttenwesen im Königreiche Sachsen, 1877, 42-53.
  4. 1951Weiss-Frondel, Judith (1951) Studies of uranium minerals (VII): Zeunerite. American Mineralogist, 36 (3-4) 249-255
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zeunerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zeunerite-4397},
  note      = {Accessed 2026-05-11}
}