Masutomilite

KLiAlMn2+(Si3Al)O10(F,OH)2
IMA status
  • Approved
IMA symbol
Msu
Also known as
  • Masutomiliet

Where it forms, where it's found

Geological setting

Granite pegmatite

Type locality
Tanakami-yama (Tanokami-yama)
  1. Otsu City
  2. Shiga Prefecture
  3. Japan
10recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Pale purplish-pink
Tenacity
flexible
Cleavage
Perfect

(001)

Density
2.90 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 28 – 35° · 2V calc = 18°
Refractive index
1.534 – 1.574
Surface relief
Moderate
Principal indices
nα 1.534 – 1.536 · nβ 1.569 – 1.570 · nγ 1.570 – 1.574
Pleochroism
Visible

X = Z = colorless to pale pink, Y = purple.

Dispersion
r > v, very weak.
Extinction
Y = b; Z ∧ a = 2°-4°.
Notes

Absorption: Y > Z > X.

Michel-Lévy diagramhighlighted lineδ = 0.0370
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]370 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation370 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2
Cell parameters
a = 5.262(2) Å · b = 9.102(3) Å · c = 10.094(3) Å
Cell angles
β = 100.83(2) °
Ratio a:b:c
1 : 1.730 : 1.918
Z
2
Type-locality form

Zoned mica crystal 10 cm across and 1 cm thick

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
40.75%
14SiSiliconSilicon328.08584.255
17.88%
25MnManganeseManganese154.93854.938
11.66%
13AlAluminiumAluminium226.98253.964
11.45%
19KPotassiumPotassium139.09839.098
8.30%
9FFluorineFluorine218.99837.996
8.06%
3LiLithiumLithium16.9406.940
1.47%
1HHydrogenHydrogen21.0082.016
0.43%
Total471.195100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Fe
  • Na
  • Rb
  • H2O

Synonyms

  • Masutomiliet

In other languages

German
IMA 1974-046 · Masutomilith
Italian
Masutomilite
Japanese
益富雲母

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20MasutomiliteSpecies
Dana
8th ed.

71.02.2b.12

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2b— unnamed intermediate level —Group
  • 71.02.2b.12MasutomiliteSpecies
CIM

16.16.11

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.16Aluminosilicates of MnGroup
  • 16.16.11MasutomiliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1975Nagashima, K. (1975) A new mineral masutomilite from Mt Tanakami, Otsu City, Shiga Prefecture. Chigaku Kenkyu: 26: 319-324.
  2. 1976Harada, K., Honda, M., Nagashima, K., Kanisawa, S. (1976) Masutomilite, manganese analog of zinnwaldite, with special reference to masutomilite-lepidolite-zinnwaldite series. Mineralogical Journal (Japan): 8(2): 95-109.
  3. 1977Fleischer, Michael, Cabri, Louis J., Nickel, Ernest H., Pabst, Adolf (1977) New Mineral Names. American Mineralogist, 62 (5-6) 593-600
  4. 1983Nemec, D. (1983) Masutomilite in lithium pegmatites of West-Moravia, Czechoslovakia. Neues Jahrbuch für Mineralogie Monatshefte: (12): 537-540.
  5. 1986Mizota, T., Kato, T., Harada, K. (1986) The crystal structure of masutomilite, Mn analog of zinnwaldite. Mineralogical Journal (Japan): 13: 13-21.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Masutomilite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/masutomilite-2588},
  note      = {Accessed 2026-05-11}
}