Merrihueite

(K,Na)2(Fe2+,Mg)5Si12O30
IMA status
  • Approved
IMA symbol
Mhu
Discovered
1965
Also known as
  • IMA1965-020
  • Merrihueiet

Where it forms, where it's found

Geological setting

Chondrite meteorite.

Type locality
Mezö-Madaras meteorite (Fekete
  1. Madaras
  2. Maros
  3. Mesö-Madarasz
  4. Mezoe-Madaras
  5. Weiler [NHM Cat.])
  6. Harghita County
  7. Romania

46.5000°, 25.7333°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Greenish-blue
Density
2.87 g/cm³

Optical

Optical type
Uniaxial (-) · 2V measured = 5 – 10°
Refractive index
1.559 – 1.592
Surface relief
Moderate
Principal indices
nω 1.57 · nε 1.559 – 1.592
Birefringence
Low to moderate
Pleochroism
Visible

Colorless to greenish-blue

Notes

Anomalously biaxial.

Michel-Lévy diagramhighlighted lineδ = 0.0055
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]55 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation55 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P6/mcc
Cell parameters
a = 10.16(6) Å · c = 14.32(6) Å
Z
2
Type-locality form

Aggregates, to 150 µm, of smaller individuals.

Comment

By analogy to osumilite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3015.999479.970
35.77%
14SiSiliconSilicon1228.085337.020
25.11%
26FeIronIron555.845279.225
20.81%
12MgMagnesiumMagnesium524.305121.525
9.05%
19KPotassiumPotassium239.09878.196
5.83%
11NaSodiumSodium222.99045.980
3.43%
Total1341.916100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Mn
  • Ca

Synonyms

  • IMA1965-020
  • Merrihueiet

In other languages

French
Merrihueite
German
IMA 1965-020 · Merrihueit
Italian
Merrihueite

Classification

Strunz
10th ed.

9.CM.05

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CM[Si6O18]12- 6-membered double rings (sechser-Doppelringe)Group
  • 9.CM.05MerrihueiteSpecies
Dana
8th ed.

63.02.1a.05

  • 63Cyclosilicates Condensed RingsClass
  • 63.02Condensed Rings (Milarite - Osumilite group)Type
  • 63.02.1a— unnamed intermediate level —Group
  • 63.02.1a.05MerrihueiteSpecies
CIM

14.24.5

  • 14Silicates not Containing AluminumClass
  • 14.24Silicates of Fe, Mg and alkalisGroup
  • 14.24.5MerrihueiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1965Fleischer, Michael (1965) New Mineral Names. American Mineralogist, 50 (11-12) 2096-2111
  2. 1965Dodd, R.T., Van Schmus, W.R., Marvin, U.B. (1965) Merrihueite, a new alkali-ferromagnesian silicate from the Mezö-Madaras chondrite. Science: 149: 972-974.
  3. 1972Khan, A.A., Baur, W.H., Forbes, W.C. (1972) Synthetic magnesian merrihueite, dipotassium pentamagnesium dodecasilicate. Tetrahedral magnesiosilicate framework crystal structure. Acta Crystallographica: B28: 267-272.
  4. 1989Armbruster, T. (1989) Crystal chemistry of double-ring silicates: structure of roedderite at 100 and 300 K. European Journal of Mineralogy: 1: 715-718.
  5. 2001(2001) Merrihueite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Merrihueite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/merrihueite-2652},
  note      = {Accessed 2026-05-11}
}