Where it forms, where it's found
- Geological setting
Late stage oxidation of vivianite in a granite pegmatite
Phosphate veins in ironstone Phosphatic sedimentary units
- Type locality
- Big Chief Mine
- Glendale
- Keystone Mining District
- Pennington County
- South Dakota
- USA
43.8650°, -103.3819°
Physical
Optical
- Optical type
- Biaxial (+) · 2V measured = 85° · 2V calc = 90°
- Refractive index
- 1.6 – 3
- Surface relief
- Very high
- Principal indices
- nα 1.600 – 3 · nβ 1.640 – 3 · nγ 1.685 – 3
- Birefringence
- 0.50
- Pleochroism
- Visible
X blue to blue green, Y,Z yellow green
- Dispersion
- very weak
- Extinction
- X perpendicular to {010}, Y parallel {110}
- UV response
- Not fluorescent
Crystallography
- Space group
- P-1
- Cell parameters
- a = 7.989(1) Å · b = 9.321(2) Å · c = 4.629(1) Å
- Cell angles
- α = 97.34(1) ° · β = 95.96(1) ° · γ = 108.59(2) °
- Ratio a:b:c
- 1 : 1.167 : 0.579
- Unit cell volume
- 320.18 ų
- Z
- 1
- Morphology
Bladed crystals, often with irregular acute multiple terminations.
- Twinning
(110)
- Type-locality form
Blue black or green black bladed crystals
Chemical composition
Synonyms
- IMA1973-049
- Kerchenite-alpha
- Metavivianiet
In other languages
- German
- IMA 1973-049 · Metavivianit
- Italian
- Metavivianite
- Chinese
- 三斜蓝铁矿 · 三斜藍鐵礦
Classification
8.DC.25
- 8Phosphates, Arsenates, VanadatesClass
- 8.DPhosphates, etc. with additional anions, with H2ODivision
- 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
- 8.DC.25MetavivianiteSpecies
40.11.09.04
- 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
- 40.11— unnamed intermediate level —Type
- 40.11.09— unnamed intermediate level —Group
- 40.11.09.04MetavivianiteSpecies
19.13.12
- 19PhosphatesClass
- 19.13Phosphates of Fe aloneGroup
- 19.13.12MetavivianiteSpecies
Group, growth & confusion
Literature, links & citation
- 1974Ritz, Charles, Essene, Eric J., Peacor, and Donald R. (1974) Metavivianite, Fe3(PO4)2·8H2O, a new mineral. American Mineralogist, 59 (9-10) 896-899
- 1980Chevalier, Raymond; Gaspérin, Madeleine; Poullen, Jean Francois (1980): Atomic structure of an oxidized vivianite. Comptes Rendus des Seances de l'Academie des Sciences, D291, 661-663.
- 1981Cabri, Louis J., Fleischer, Michael, Pabst, Adolf (1981) New Mineral Names. American Mineralogist, 66 (9-10) 1099-1103
- 1982Dormann, Jean-Louis, Gasperin, Madeleine, Poullen, Jean-François (1982) Étude structurale de la séquence d'oxydation de la vivianite Fe3(PO4)2 • 8 H2O. Bulletin de Minéralogie, 105 (2) 147-160 doi:10.3406/bulmi.1982.7597DOI: 10.3406/bulmi.1982.7597
- 1985Sameshima, T., Henderson, G. S., Black, P. M., Rodgers, K. A. (1985) X-ray diffraction studies of vivianite, metavivianite, and barićite. Mineralogical Magazine, 49 (350) 81-85 doi:10.1180/minmag.1985.049.350.11 DOI: 10.1180/minmag.1985.049.350.11
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Metavivianite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/metavivianite-2695},
note = {Accessed 2026-05-11}
}



