Metavivianite

Fe2+Fe3+2(PO4)2(OH)2 · 6H2O
IMA status
  • Approved
IMA symbol
Mviv
Discovered
1974
Also known as
  • IMA1973-049
  • Kerchenite-alpha
  • Metavivianiet

Where it forms, where it's found

Geological setting

Late stage oxidation of vivianite in a granite pegmatite

Phosphate veins in ironstone Phosphatic sedimentary units

Type locality
Big Chief Mine
  1. Glendale
  2. Keystone Mining District
  3. Pennington County
  4. South Dakota
  5. USA

43.8650°, -103.3819°

27recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark blue to blue-black · dark green to green-black
Streak
Blue or greenish blue
Tenacity
sectile
Cleavage
Perfect

(110)

Density
2.69 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 85° · 2V calc = 90°
Refractive index
1.6 – 3
Surface relief
Very high
Principal indices
nα 1.600 – 3 · nβ 1.640 – 3 · nγ 1.685 – 3
Birefringence
0.50
Pleochroism
Visible

X blue to blue green, Y,Z yellow green

Dispersion
very weak
Extinction
X perpendicular to {010}, Y parallel {110}
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.5000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]5000 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation5000 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 7.989(1) Å · b = 9.321(2) Å · c = 4.629(1) Å
Cell angles
α = 97.34(1) ° · β = 95.96(1) ° · γ = 108.59(2) °
Ratio a:b:c
1 : 1.167 : 0.579
Unit cell volume
320.18 ų
Z
1
Morphology

Bladed crystals, often with irregular acute multiple terminations.

Twinning

(110)

Type-locality form

Blue black or green black bladed crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
51.24%
26FeIronIron355.845167.535
33.54%
15PPhosphorusPhosphorus230.97461.948
12.40%
1HHydrogenHydrogen141.00814.112
2.82%
Total499.579100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1973-049
  • Kerchenite-alpha
  • Metavivianiet

In other languages

German
IMA 1973-049 · Metavivianit
Italian
Metavivianite
Chinese
三斜蓝铁矿 · 三斜藍鐵礦

Classification

Strunz
10th ed.

8.DC.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.25MetavivianiteSpecies
Dana
8th ed.

40.11.09.04

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.11— unnamed intermediate level —Type
  • 40.11.09— unnamed intermediate level —Group
  • 40.11.09.04MetavivianiteSpecies
CIM

19.13.12

  • 19PhosphatesClass
  • 19.13Phosphates of Fe aloneGroup
  • 19.13.12MetavivianiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1974Ritz, Charles, Essene, Eric J., Peacor, and Donald R. (1974) Metavivianite, Fe3(PO4)2·8H2O, a new mineral. American Mineralogist, 59 (9-10) 896-899
  2. 1980Chevalier, Raymond; Gaspérin, Madeleine; Poullen, Jean Francois (1980): Atomic structure of an oxidized vivianite. Comptes Rendus des Seances de l'Academie des Sciences, D291, 661-663.
  3. 1981Cabri, Louis J., Fleischer, Michael, Pabst, Adolf (1981) New Mineral Names. American Mineralogist, 66 (9-10) 1099-1103
  4. 1982Dormann, Jean-Louis, Gasperin, Madeleine, Poullen, Jean-François (1982) Étude structurale de la séquence d'oxydation de la vivianite Fe3(PO4)2 • 8 H2O. Bulletin de Minéralogie, 105 (2) 147-160 doi:10.3406/bulmi.1982.7597DOI: 10.3406/bulmi.1982.7597
  5. 1985Sameshima, T., Henderson, G. S., Black, P. M., Rodgers, K. A. (1985) X-ray diffraction studies of vivianite, metavivianite, and barićite. Mineralogical Magazine, 49 (350) 81-85 doi:10.1180/minmag.1985.049.350.11 DOI: 10.1180/minmag.1985.049.350.11
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metavivianite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metavivianite-2695},
  note      = {Accessed 2026-05-11}
}