Marićite

NaFe2+(PO4)
IMA status
  • Approved
IMA symbol
Mrć
IMA approved
1976
Also known as
  • Marićiet

Where it forms, where it's found

Geological setting

In veined phosphatic ironstone

Type locality
Big Fish River
  1. Dawson mining district
  2. Yukon
  3. Canada

68.4738°, -136.4874°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark gray · Brown to pale brown · nearly colorless
Streak
White to light gray white
Tenacity
brittle
Cleavage
None Observed

May follow the splintery pattern of the mineral's growth

Fracture
Irregular/Uneven · Splintery
Density
3.66 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 44°
Refractive index
1.676 – 1.698
Surface relief
High
Principal indices
nα 1.676 · nβ 1.695 · nγ 1.698
Birefringence
0.022
Pleochroism
Non-pleochroic
Dispersion
r>v, weak
Extinction
XYZ=abc
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pmna
Cell parameters
a = 6.867 Å · b = 8.989 Å · c = 5.049 Å
Ratio a:b:c
1 : 1.309 : 0.735
Z
4
Morphology

Radial aggregates.

Comment

Pmnb; Can Min (1977) 15:518 (structure) pseudohexagonal

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
36.82%
26FeIronIron155.84555.845
32.13%
15PPhosphorusPhosphorus130.97430.974
17.82%
11NaSodiumSodium122.99022.990
13.23%
Total173.805100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Marićiet

In other languages

French
Maricite
German
IMA 1976-024 · Marićit
Italian
marićite
Arabic
ماريسيت

Classification

Strunz
10th ed.

8.AC.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.20MarićiteSpecies
Dana
8th ed.

38.01.02.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.01ABXO4Type
  • 38.01.02— unnamed intermediate level —Group
  • 38.01.02.01MarićiteSpecies
CIM

19.1.15

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.15MarićiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1977Le Page, Y., Donnay, G. (1977) The crystal structure of the new mineral marićite. The Canadian Mineralogist, 15. 518-521
  2. 1977Sturman, B. D., Mandarino, Joseph A., Corlett, M. I. (1977) Marićite, a sodium iron phosphate, from the Big Fish River area, Yukon Territory, Canada. The Canadian Mineralogist, 15 (3) 396-398
  3. 1979Fleischer, Michael, Chao, George Y., Mandarino, J. A. (1979) New mineral names. American Mineralogist, 64 (5-6) 652-659
  4. 1992Robinson, George W., Van Velthuizen, Jerry, Ansell, H. Gary, Sturman, B. Darko (1992) Mineralogy of the Rapid Creek and Big Fish River Area, Yukon Territory. The Mineralogical Record, 23 (4) 1-47
  5. 1999Tremaine, Peter R., Xiao, Caibin (1999) Enthalpies of formation and heat capacity functions for maricite, NaFePO4(cr), and sodium iron(III) hydroxy phosphate, Na3Fe(PO4)2· (Na4/3H2/3O)(cr) The Journal of Chemical Thermodynamics, 31 (10) 1307-1320 doi:10.1006/jcht.1999.0542DOI: 10.1006/jcht.1999.0542
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Marićite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/maricite-2576},
  note      = {Accessed 2026-05-11}
}