Villiaumite

NaF
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vll
Discovered
1908

Where it forms, where it's found

Geological setting

Small miarolytic cavities in nepheline syenite.

Alkalic rocks.

Type locality
Rouma Island
  1. Los Archipelago (Los Islands)
  2. Conakry Region
  3. Guinea
40recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark carmine-red · dark red · light orange · pink

The reddish colours were thought to be due to structural defects, caused by irradiation (Sørensen, 1973; Jahn et al., 2014). However, according to Calas et al. (2021) the red colour comes from metal Na nanoparticles, 2.5–3 nm in diameter. <br> Villiaumite samples began to change color very slowly after being heated above 300 °C in a muffle furnace. Subsequent color changes required heating at increasingly higher temperatures for approximately 48–72 h. Samples of the reddish mineral villiaumite turned orange, pink and finally colorless (at approximately at 430 °C)[[1]]. Heating is accompanied by strong thermoluminescence (Sørensen, 1973).

Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001).

Density
2.79 g/cm³

Optical

Optical type
Isotropic
Surface relief
Low
Principal indices
n 1.327 – 1.328
Pleochroism
Strong

E = yellow O = pink to deep carmine

UV response
Dark red to orange and yellow fluorescence under SW and LW UV.
Notes

Weak anomalous birefringence.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.328

Crystallography

Crystal system
Isometric
Space group
#222
Cell parameters
a = 4.6342 Å
Z
4
Morphology

Cubic, often rounded crystals; massive, granular.

Parting
Translation gliding with T(011), t[011], and probably also T(001), t[011].
Type-locality form

Carmine red to dark violet masses 1-3 mm in size.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
11NaSodiumSodium122.99022.990
54.75%
9FFluorineFluorine118.99818.998
45.25%
Total41.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

In other languages

French
villiaumite
German
Villiaumit
Spanish
Villiaumita
Italian
Villiaumite
Portuguese
villiaumita · Villiaumite
Japanese
ビリオム石
Chinese
氟鹽
Russian
Виллиомит

Classification

Strunz
10th ed.

3.AA.20

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.20VilliaumiteSpecies
Dana
8th ed.

09.01.01.03

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.01Halite GroupGroup
  • 09.01.01.03VilliaumiteSpecies
CIM

8.1.2

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.1Halides of the alkali metals and ammoniumGroup
  • 8.1.2VilliaumiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1908Lacroix, A. (1908): Sur l'existance du fluorure de sodium cristallisé comme èlèment des syènites nèphèliniques des Îles de Los. Comptes Rendu, Academie des Sciences, Paris: 146(5): 213-216.
  2. 1921Davey (1921): Physical Review, a Journal of Experimental and Theoretical Physics.
  3. 1923Davey (1923): Physical Review, a Journal of Experimental and Theoretical Physics: 21: 143.
  4. 1927Barth, T. & Lunde, G. (1927): Über das Mineral Villiaumit. Centralblatt für Mineralogie, Geologie und Paläontologie, 1927, 57-66 (in German).
  5. 1953Swanson, H.E., Tatge, E. (1953) Standard X-ray Diffraction Powder Patterns. United States Department of Commerce, National Bureau of Standards, Circular 539, 1, 63-64.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Villiaumite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/villiaumite-4181},
  note      = {Accessed 2026-05-11}
}