Natrozippeite

Na5(UO2)8(SO4)4O5(OH)3 · 12H2O
IMA status
  • Approved
IMA symbol
Nzip
Discovered
1971
IMA approved
1971
Also known as
  • IMA1971-004
  • Na Zippeit
  • Na Zippeite
  • +2 more

Where it forms, where it's found

Geological setting

Post-mine encrustation and/or supergene in origin.

A secondary mineral of uranium mineral deposits, frequently if not most commonly as post-mine growths.

Type locality
Happy Jack Mine (Blue Dike Mine)
  1. White Canyon Mining District
  2. San Juan County
  3. Utah
  4. USA

37.7522°, -110.2928°

53recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellow to greenish yellow or yellowish green
Streak
Yellow
Cleavage
Perfect

Parallel to flattening of grains.

Fracture
Micaceous
Density
4.517 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80° · 2V calc = 80°
Refractive index
1.63 – 1.738
Surface relief
High
Principal indices
nα 1.63 · nβ 1.69 · nγ 1.738
Birefringence
0.100-0.109
Pleochroism
Strong

Colorless to yellow

Dispersion
relatively strong
UV response
Bright yellow in both SW and LW.
Michel-Lévy diagramhighlighted lineδ = 0.1000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1000 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1000 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 17.6425(11) Å · b = 14.6272(9) Å · c = 17.6922(11) Å
Cell angles
β = 104.461(1) °
Ratio a:b:c
1 : 0.829 : 1.003
Morphology

Found as earthy to velvety patches or crusts of earthy yellow mineral, rarely as micro-crystals.

Twinning

Reported as common, but no morphology given.

Type-locality form

Velvety crusts of minute yellow masses and rare crystals.

Comment

Pronounced pseudo-cells may be 5 x b

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium8238.0291904.232
63.34%
8OOxygenOxygen5215.999831.948
27.67%
16SSulfurSulfur432.060128.240
4.27%
11NaSodiumSodium522.990114.950
3.82%
1HHydrogenHydrogen271.00827.216
0.90%
Total3006.586100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1971-004
  • Na Zippeit
  • Na Zippeite
  • Natrozippeiet
  • Sodium-Zippeite

In other languages

German
IMA 1971-004 · Natrozippeit
Italian
Natrozippeite · Sodio-zippeite

Classification

Strunz
10th ed.

7.EC.05

  • 7SulfatesClass
  • 7.EUranyl sulfatesDivision
  • 7.ECWith medium-sized and large cationsGroup
  • 7.EC.05NatrozippeiteSpecies
Dana
8th ed.

31.10.04.02

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.10MiscellaneousType
  • 31.10.04Zippeite GroupGroup
  • 31.10.04.02NatrozippeiteSpecies
CIM

25.8.10

  • 25SulphatesClass
  • 25.8Sulphates of Sb, V, Cr and UGroup
  • 25.8.10NatrozippeiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1976Frondel, C., Ito, J., Honea, R.M., Weeks, A.M. (1976) Mineralogy of the zippeite group. The Canadian Mineralogist: 14: 429-436.
  2. 1997Gaines, Richard V.; Skinner, H. Catherine W.; Foord, Eugene E.; Mason, Brian; Rosenzweig, Abraham; King, Vandall T. (1997) Dana's New Mineralogy (8th ed.). Wiley-Interscience. 1872 pp.
  3. 1997Ondruš, P., Veselovský, F., Hloušek, J., Skála, R., Vavřín, I., Frýda, J., Čejka, J., Gabašová, A. (1997) Secondary minerals of the Jáchymov (Joachimsthal) ore district. Journal of the Czech Geological Society, 42 (4). 3-69
  4. 2003Burns, P. C., Deely, K. M., Hayden, L. A. (2003) The crystal chemistry of the zippeite group. The Canadian Mineralogist, 41 (3). 687-706 doi:10.2113/gscanmin.41.3.687 DOI: 10.2113/gscanmin.41.3.687
  5. 2005(2005) Natrozippeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrozippeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrozippeite-3694},
  note      = {Accessed 2026-05-11}
}