Osakaite

Zn4(SO4)(OH)6 · 5H2O
IMA status
  • Approved
IMA symbol
Ok
Discovered
1999
IMA approved
2006
Also known as
  • IMA2006-049
  • Osakaiet

Where it forms, where it's found

Geological setting

Oxide zone of hydrothermal vein cutting shale at abandoned zinc mine.

Type locality
Hirao mine
  1. Onsen-cho
  2. Minoh City
  3. Osaka Prefecture
  4. Japan

34.8333°, 135.4667°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale blue to colorless or white
Streak
White to pale blue
Tenacity
flexible
Cleavage
Perfect

(001)

Density
2.70 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 27.2°
Refractive index
1.532 – 1.567
Surface relief
Moderate
Principal indices
nα 1.532 · nβ 1.565 · nγ 1.567
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 8.358 Å · b = 8.337 Å · c = 11.027 Å
Cell angles
α = 94.97 ° · β = 83.16 ° · γ = 119.6 °
Ratio a:b:c
1 : 0.997 : 1.319
Unit cell volume
663 ų
Z
2
Type-locality form

Pale blue to colorless platy crystals

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc465.380261.520
47.58%
8OOxygenOxygen1515.999239.985
43.66%
16SSulfurSulfur132.06032.060
5.83%
1HHydrogenHydrogen161.00816.128
2.93%
Total549.693100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2006-049
  • Osakaiet

In other languages

German
IMA 2006-049 · Osakait
Italian
osakaite
Japanese
大阪石

Classification

Strunz
10th ed.

7.DE.40

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DEWith only medium-sized cations; unclassifiedGroup
  • 7.DE.40OsakaiteSpecies
Dana
8th ed.

31.04.07.02

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.04(AB)4(XO4)Zq·xH2OType
  • 31.04.07— unnamed intermediate level —Group
  • 31.04.07.02OsakaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1986Bear, I. J., Grey, I. E., Madsen, I. C., Newnham, I. E., Rogers, L. J. (1986) Structures of the basic zinc sulfates 3Zn(OH)2.ZnSO4.mH2O, m = 3 and 5. Acta Crystallographica Section B Structural Science, 42 (1) 32-39 doi:10.1107/s0108768186098622DOI: 10.1107/s0108768186098622
  2. 2007Ohnishi, M., Kusachi, I., Kobayashi, S. (2007) Osakaite, Zn4SO4(OH)6·5H2O, a new mineral species from the Hirao mine, Osaka, Japan. The Canadian Mineralogist, 45 (6) 1511-1517 doi:10.3749/canmin.45.6.1511 DOI: 10.3749/canmin.45.6.1511
  3. 2013(2013) Osakaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Osakaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/osakaite-31498},
  note      = {Accessed 2026-05-11}
}